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1145-93-3 - Diethyl 4-methoxybenzylphosphonate, 98+% - 4-Methoxybenzylphosphonic acid diethyl ester - L05226 - Alfa Aesar

L05226 Diethyl 4-methoxybenzylphosphonate, 98+%

Codice CAS
1145-93-3
Sinonimi
4-Methoxybenzylphosphonic acid diethyl ester

Dimensioni Prezzo ($) Quantità Disponibilità
10g 64,70
50g 237,00
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Diethyl 4-methoxybenzylphosphonate, 98+%

MDL
MFCD00015662
EINECS
214-548-5

Proprietà chimiche

Formula
C12H19O4P
Peso formula
258.25
Punto di ebollizione
136-138°/0.7mm
Punto di infiammabilità
>110°(230°F)
Densità
1.500
Indice di rifrazione
1.5045
Solubilità
Not miscible in water.

Applicazioni

Diethyl 4-methoxybenzylphosphonate is used in synthesis of C-aryl glycosides. It acts as a reactant for synthesis of γ -Monofluorinated goniothalamin analogs via ring-opening hydrofluorination, stilbenoid derivatives with neuroprotective activity, resveratrol-chroman hybrids with antioxidant activity, Oligostilbenoids using regioselective cyclodehydration and arylation.

Note

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible materials are Strong oxidizing agents.

Letteratura

Frédérique Hauss,;Jiawei Liu; Alessandro Michelucci; Djalil Coowar; Eleonora Morga; Paul Heuschling; Bang Luu. Dual bioactivity of resveratrol fatty alcohols: differentiation of neural stem cells and modulation of neuroinflammation.Bioorganic & Medicinal Chemistry Letters.2007,17 (15), 4218-4222.

Jie Yang; Guo-Yun Liu; Dong-Liang Lu; Fang Dai; Yi-Ping Qian; Xiao-Ling Jin; Bo Zhou. Hybrid-increased radical-scavenging activity of resveratrol derivatives by incorporating a chroman moiety of vitamin E.Chemistry: A European Journal. 2010,16 (43), 12808-12813.

Used in synthesis of C-aryl glycosides: J. Org. Chem., 57, 5670 (1992).

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni precauzionali: P260-P201-P280-P304+P340-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves/protective clothing/eye protection/face protection. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Beilstein
2125148
Codice tariffe armonizzato
2931.39
TSCA
No

Raccomandato

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    Diethyl benzylphosphonate, 99%
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    2-Methoxybenzyl alcohol, 99%
  • A15190

    Diethyl 4-methylbenzylphosphonate, 98+%
  • A16242

    Calcium hydride, coarse powder, ca 92%
  • A18882

    (1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide, 98%

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