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14916-80-4 - 3-Octyn-1-ol, 96% - L05414 - Alfa Aesar

L05414 3-Octyn-1-ol, 96%

Codice CAS
14916-80-4
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
5g 44,50
25g 154,00
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3-Octyn-1-ol, 96%

MDL
MFCD00039552
EINECS
238-986-1

Proprietà chimiche

Formula
CH3(CH2)3C≡C(CH2)2OH
Peso formula
126.20
Punto di ebollizione
86-88°/9mm
Punto di infiammabilità
>110°(230°F)
Densità
0.883
Indice di rifrazione
1.4540
Solubilità
It is soluble in water.

Applicazioni

3-Octyn-1-ol, is used for a study of the reduction of acetylenic compounds, including this alcohol, to (E)-alkenes by alkali metals in liquid ammonia. Some other applications includes as corrosion inhibitor formulation, metal complex solution, solvent stabilizer, biodegradable chemical intermediate to make pharmaceuticals, chemical compound synthesis and reagents

Note

Stable under normal temperatures and pressures. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Keep away from oxidizing agents.

Letteratura

S Chandrasekhar.; C Narsihmulu.; G Chandrashekar. Pd/CaCO 3 in liquid poly (ethylene glycol)(PEG): an easy and efficient recycle system for partial reduction of alkynes to cis-olefins under a hydrogen atmosphere. Tetrahedron letters. 2004, 45,(11), 2421-2423.

SE Denmark.; W Pan. Intramolecular Hydrosilylation and Silicon-Assisted Cross-Coupling: An Efficient Route to Trisubstituted Homoallylic Alcohols. Organic letters. 2001, 3,(1), 61-64.

For a study of the reduction of acetylenic compounds, including this alcohol, to (E)-alkenes by alkali metals in liquid ammonia, see: Eur. J. Org. Chem., 775 (1999).

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni precauzionali: P260u-P201-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310a-P405-P501a

Obtain special instructions before use. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Beilstein
1739950
Codice tariffe armonizzato
2905.29
TSCA
Yes

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