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625-38-7 - Vinylacetic acid, 96% - 3-Butenoic acid - L07557 - Alfa Aesar

L07557 Vinylacetic acid, 96%

Codice CAS
625-38-7
Sinonimi
3-Butenoic acid

Vinylacetic acid, 96%

MDL
MFCD00002782
EINECS
210-892-5

Proprietà chimiche

Formula
C4H6O2
Peso formula
86.09
Punto di fusione
-39°
Punto di ebollizione
162-163°
Punto di infiammabilità
65°(149°F)
Densità
1.012
Indice di rifrazione
1.4240
Solubilità
Fully miscible.

Applicazioni

Vinylacetic acid used in the preparation of strained nitroso Diels-Aldrer adducts which undergo a domino ROC metathesis in the presence of Ru-carbene catalysts and olefins. It is used in the synthesis of polyethylene glycolated boltorn coatings. It was used to study the inhibition of the enzyme-catalyzed conversion of D-tyrosyl- phenylalanyl-glycine to D-tyrosyl-phenylaline amide by non-peptide carboxylic acids.

Note

Store at 4°C. Protect from heat. Store away from oxidizing agents. Incompatible with oxidizing agents, heat, Bases, Reducing agents.

Letteratura

Marco Laurenti; Pablo Guardia; Rafael Contreras-Cáceres; Jorge Pérez-Juste; Antonio Fernandez-Barbero; Enrique Lopez-Cabarcos; Jorge Rubio-Retama. Synthesis of thermosensitive microgels with a tunable magnetic core.Langmuir.2011, 27 (17), 10484-10491.

A F Bradbury; J Mistry; B A Roos; D G Smyth. 4-Phenyl-3-butenoic acid, an in vivo inhibitor of peptidylglycine hydroxylase (peptide amidating enzyme).European Journal of Biochemistry.1990, 189 (2), 363-368.

ß-Unsaturated acids, including vinylacetic acid, undergo bromolactonization with bromine in the presence of bicarbonate giving a mixture of ß- and -lactones: J. Org. Chem., 55, 2487 (1990). Further treatment of the lactone mixture with AgNO3 in acetic acid provides a route to butenolides: Tetrahedron Lett., 34, 1411 (1993).

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H227-H314-H318

Combustible liquid. Causes severe skin burns and eye damage. Causes serious eye damage.

Dichiarazioni precauzionali: P210u-P260u-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Beilstein
1699159
Classe di rischio
8
Gruppo di imballaggio
II
Codice tariffe armonizzato
2916.19
TSCA
No

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