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trans-5-Decene has been used to characterize the effect of cyclization and size on the stability of Criegee intermediates formed in ozonolysis. It has been added to phenoxathiin cation radical in acetonitrile solution to form bis(10-phenoxathiiniumyl) alkane adducts.
Greg T Drozd and Neil M Donahue.Pressure dependence of stabilized Criegee intermediate formation from a sequence of alkenes. ournal of Physical Chemistry A: Molecules, Spectroscopy, Kinetics, Environment and General Theory. 2011, 115 (17), 4381-4387.
Bing-Jun Zhao et. al. Addition of the phenoxathiin cation radical to alkenes and nonconjugated dienes. Formation of (E)- and (Z)-(10-phenoxathiiniumyl)alkenes and (E)- and (Z)-(10-phenoxathiiniumyl)dienes on basic alumina. . Journal of Organic Chemistry. 2007 , 7216), 6154-6161.
Dichiarazioni di rischio (UE): H226
Flammable liquid and vapour.
Dichiarazioni precauzionali: P210-P280a-P240-P241-P303+P361+P353-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves and eye/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Dispose of contents/container in accordance with local/regional/national/international regulations.