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Norbornene is used as a monomer and as an intermediate in organic synthesis. It is also used to prepare pharmaceutical intermediates and specialty fragrances. It reacts with ethylene to get cyclic olefin copolymer. Further, it is used in transition metal catalysis to affect migration of electrophilic transition metals. It acts as a monomer in ring-opening metathesis polymerizations with the Grubbs' catalyst. Its polymer, polynorbornene is used in the rubber industry for anti-vibration, anti-impact in personal protective equipment and grip improvement in toy tires, racing tires and transmission system.
Best, M.; Degen, A.; Baalmann, M.; Schmidt, T. T.; Wombacher, R. Two-step protein labeling by using lipoic acid ligase with norbornene substrates and subsequent inverse-electron demand Diels-Alder reaction. Chembiochem 2015, 16 (8), 1158-1162.
Shen, P. X.; Wang, X. C.; Wang, P.; Zhu, R. Y.; Yu, J. Q. Ligand-Enabled Meta-C-H Alkylation and Arylation Using a Modified Norbornene. J. Am. Chem. Soc. 2015, 137 (36), 11574-11577.
Dichiarazioni di rischio (UE): H228-H319
Flammable solid. Causes serious eye irritation.
Dichiarazioni precauzionali: P210-P273-P305+P351+P338-P337+P313
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid release to the environment. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.