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937-41-7 - Phenyl acrylate, 97% - Acrylic acid phenyl ester - L11819 - Alfa Aesar

L11819 Phenyl acrylate, 97%

Codice CAS
937-41-7
Sinonimi
Acrylic acid phenyl ester

Dimensioni Prezzo ($) Quantità Disponibilità
5g 65,60
25g 250,00
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Phenyl acrylate, 97%

MDL
MFCD00048145
EINECS
213-329-1

Proprietà chimiche

Formula
C6H5O2CCH=CH2
Peso formula
148.16
Punto di ebollizione
89-90°/12mm
Densità
1.076
Indice di rifrazione
1.5210
Solubilità
Insoluble in water.

Applicazioni

Phenyl acrylate reacts with benzaldehyde to produce 2-(hydroxy-phenyl-methyl)-acrylic acid phenyl ester.

Note

Incompatible with strong oxidizing agents. Store at 4°C. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

Letteratura

S.-K. L. Li.; J. E. Guillet. Studies of the Photo-Fries Reaction in Solid Poly(phenyl acrylate). Macromolecules. 1977, 10 (4), 840-844.

Makoto Azukizawa.; Bunichiro Yamada.; David J. T. Hill.; Peter J. Pomery. Radical polymerization of phenyl acrylate as studied by ESR spectroscopy: concurrence of propagating and mid-chain radicals. Macromolecular Chemistry and Physics. 2000, 201 (7), 774-781.

Aryl acrylates undergo the Baylis-Hillman reaction with aldehydes in the presence of 1,4-Diazabicyclo[2.2.2]octane, A14003 much more rapidly than alkyl acrylates. Reaction with a second molecule of aldehyde can occur to give a cyclic acetal product: Tetrahedron Lett., 37, 1715 (1996):

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H315-H319-H335-H411-H401

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Toxic to aquatic life with long lasting effects. Toxic to aquatic life.

Dichiarazioni precauzionali: P261-P273-P280-P305+P351+P338-P304+P340-P362-P312-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Beilstein
2041124
Classe di rischio
9
Gruppo di imballaggio
III
Codice tariffe armonizzato
2916.12
TSCA
Yes

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