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1191-15-7 - Diisobutylaluminum hydride, 1M solution in toluene - DIBAH - DIBAL-H - L14718 - Alfa Aesar

L14718 Diisobutylaluminum hydride, 1M solution in toluene

Codice CAS
1191-15-7
Sinonimi
DIBAH
DIBAL-H

Dimensioni Prezzo ($) Quantità Disponibilità
100ml 58,50
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Diisobutylaluminum hydride, 1M solution in toluene

MDL
MFCD00008928
EINECS
214-729-9

Proprietà chimiche

Formula
C8H19Al
Peso formula
142.22
Punto di ebollizione
ca 110°
Punto di infiammabilità
4°(40°F)
Densità
0.805
Sensibilità
Moisture Sensitive
Solubilità
Reacts with water.

Applicazioni

Diisobutylaluminum hydride reduces chiral ?-silyloxy esters to the corresponding enantiomerically-pure hydroxy aldehydes. I t is used in Pd-catalyzed reductive debromination of secondary alkyl bromides, O-Debenzylation and ring opening of perbenzylated furanosides and convenient in situ generation of HZrCp2Cl from ZrCp2Cl2 and DIBAL-H.

Note

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. It is sensitive to moisture and air. Store under dry inert gas.

Letteratura

Satoru Sasatani.; Tohru Miyazaki.; Keiji Maruoka.; Hisashi Yamamoto. Diisobutylaluminum hydride a novel reagent for the reduction of oximes. Tetrahedron Letters. 1983, 24 (43), 4711-4712.

Syun-ichi Kiyooka.; Hisanori Kuroda.; Yayoi Shimasaki. 1,3-syn diastereoselective reduction of β-hydroxyketones with diisobutylaluminum hydride and tributyltin hydride. Tetrahedron Letters. 1986, 27 (26), 3009-3012.

Reduces chiral ɑ-silyloxy esters to the corresponding enantiomerically-pure hydroxy aldehydes: J. Chem. Soc., Chem. Commun., 2475 (1995).

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H224-H260-H302-H333-H314-H318-H361-H336-H373-H304

Extremely flammable liquid and vapour. In contact with water releases flammable gases which may ignite spontaneously. Harmful if swallowed. May be harmful if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. Suspected of damaging fertility or the unborn child. May cause drowsiness or dizziness. May cause damage to organs through prolonged or repeated exposure. May be fatal if swallowed and enters airways.

Dichiarazioni precauzionali: P223-P210-P231+P232-P260u-P301+P310a-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Keep away from any possible contact with water, because of violent reaction and possible flash fire. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Handle under inert gas. Protect from moisture. IF SWALLOWED: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Beilstein
4123663
Classe di rischio
4.3
Gruppo di imballaggio
I
Codice tariffe armonizzato
2931.90
TSCA
Yes
RTECS
BD0710000

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