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2917-26-2 - 1-Hexadecanethiol, 97% (dry wt.), may cont. up to 4% water - n-Hexadecyl mercaptan - Cetyl mercaptan - L15099 - Alfa Aesar

L15099 1-Hexadecanethiol, 97% (dry wt.), may cont. up to 4% water

Codice CAS
2917-26-2
Sinonimi
n-Hexadecyl mercaptan
Cetyl mercaptan

Dimensioni Prezzo ($) Quantità Disponibilità
25ml 28,40
100ml 73,10
500ml 205,00
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1-Hexadecanethiol, 97% (dry wt.), may cont. up to 4% water

MDL
MFCD00011677
EINECS
220-846-6

Proprietà chimiche

Formula
C16H34S
Peso formula
258.51
Punto di fusione
19-23°
Punto di ebollizione
334°
Punto di infiammabilità
135°(275°F)
Densità
0.846
Indice di rifrazione
1.4625
Sensibilità
Air Sensitive
Solubilità
Soluble in methanol, benzene, ether, acetone and ethyl acetate. Not miscible or difficult to mix in water.

Applicazioni

1-Hexadecanethiol is used in the study of nanoparticles and self-assembled monolayers. It is also used to prepare thiol-functionalized 1.5 nm gold nanoparticles via a ligand exchange process with triphenylphosphine-stabilized nanoparticles and in the formation of hydrophobic self-assembled monolayers (SAMs). Due to the length of the alkane chain, the resulting monolayer is highly ordered. 1-Hexadecanethiol is also employed in different fields such as biomedicine, chemical industry, also used in electroplating industry and chemical auxiliaries.

Note

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Store under inert gas. It is sensitive to air. Incompatible with oxidizing agents.

Letteratura

Daisuke Hobara.; Masayuki Ota.; Shin-ichiro Imabayashi.; Katsumi Niki.; Takashi Kakiuchi. Phase separation of binary self-assembled thiol monolayers composed of 1-hexadecanethiol and 3-mercaptopropionic acid on Au(111) studied by scanning tunneling microscopy and cyclic voltammetry. Journal of Electroanalytical Chemistry. 1998, 441 (1), 113-119.

Gossett A. Campbell.; Raj Mutharasan. Monitoring of the Self-Assembled Monolayer of 1-Hexadecanethiol on a Gold Surface at Nanomolar Concentration Using a Piezo-Excited Millimeter-Sized Cantilever Sensor. Langmuir. 2005, 21 (25), 11568-11573.

Altri riferimenti

Beilstein
1748495
Codice tariffe armonizzato
2930.90
TSCA
Yes

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