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Reagent used for palladium-catalyzed stille and suzuki-miyaura cross-couplings, microwave-heated heterogeneous palladium (pd)-catalytized reactions, ruthenium (ru)-catalyzed silylation reactions, bis(aminotropone) titanium (ti) catalysts for ethylene polymerizations, enantioselective asymmetric bromoaminocyclization and bromoaminocyclization using amino-thiocarbamate catalysts. Reagent used in preparation of common building blocks for pharmaceuticals and agrochemicals, chrysin analogs by suzuki-miyaura coupling reactions, casein kinase i inhibitors, divergent c-h functionalizations directed by sulfonamide pharmacophores in drug discovery.
Ben W Glasspoole et. al. Suzuki-Miyaura cross-couplings of secondary allylic boronic esters.. Chemical Communications. 2012, 48 (9), 1230-1232 .
Hui-Xiong Dai et. al. Divergent C-H functionalizations directed by sulfonamide pharmacophores: late-stage diversification as a tool for drug discovery.. Journal of the American Chemical Society. 2011, 133 (18), 7222-7228.
Dichiarazioni di rischio (UE): H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Dichiarazioni precauzionali: P280g-P305+P351+P338
Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.