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23357-46-2 - (R)-(-)-1,2,3,4-Tetrahydro-1-naphthylamine, ChiPros® 99+%, ee 98+% - (R)-1-Amino-1,2,3,4-tetrahydronaphthalene - L17021 - Alfa Aesar

L17021 (R)-(-)-1,2,3,4-Tetrahydro-1-naphthylamine, ChiPros® 99+%, ee 98+%

Codice CAS
23357-46-2
Sinonimi
(R)-1-Amino-1,2,3,4-tetrahydronaphthalene

Dimensioni Prezzo ($) Quantità Disponibilità
1g 28,80
5g 68,93
25g 257,50
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(R)-(-)-1,2,3,4-Tetrahydro-1-naphthylamine, ChiPros® 99+%, ee 98+%

MDL
MFCD00671629
EINECS
000-000-0

Proprietà chimiche

Formula
C10H13N
Peso formula
147.22
Punto di ebollizione
118-120°/8mm
Punto di infiammabilità
>110°(230°F)
Densità
1.035
Indice di rifrazione
1.5645
Sensibilità
Air Sensitive
Solubilità
Soluble in water (6.91g/L at 25°C).

Applicazioni

(R)-(-)-1,2,3,4-Tetrahydro-1-naphthylamine is a important organic intermediate. It can be used in agrochemical, pharmaceutical and dyestuff field. Chiral amines play an important role in stereoselective organic synthesis. They are used directly as resolving agents, building blocks or chiral auxiliaries.

Note

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Incompatible with oxidizing agents.

Letteratura

Min Qiu.; Xiang-Ping Hu.; Jia-Di Huang.; Dao-Yong Wang.; Jun Deng.; Sai-Bo Yu.; Zheng-Chao Duan.; Zhuo Zheng. Modular Phosphine-Aminophosphine Ligands Based on Chiral 1,2,3,4-Tetrahydro-1-naphthylamine Backbone: A New Class of Practical Ligands for Enantioselective Hydrogenations. Advanced Synthesis & Catalysis. 2008, 350 (17), 2683-2689.

Min Qiu.; Xiang-Ping Hu.; Dao-Yong Wang.; Jun Deng.; Jia-Di Huang.; Sai-Bo Yu.; Zheng-Chao Duan.; Zhuo Zheng. Chiral 1,2,3,4-Tetrahydro-1-naphthylamine-Derived Phosphine-Phosphoramidite Ligand (THNAPhos): Application in Highly Enantioselective Hydrogenations of Functionalized C[DOUBLE BOND]C Bonds. Langmuir. 2008, 350 (9), 1413-1418.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Beilstein
4231302
Codice tariffe armonizzato
2921.45
TSCA
No

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