Informativa e consenso per l'uso dei cookie

Accetto Il nostro sito salva piccoli pezzi di informazioni (cookie) sul dispositivo, al fine di fornire contenuti migliori e per scopi statistici. È possibile disattivare l'utilizzo di cookies modificando le impostazioni del tuo browser. Continuando la navigazione si acconsente all'utilizzo dei cookie.

55289-06-0 - 3-Methoxy-2-methylbenzoic acid, 97% - 3-Methoxy-o-toluic acid - 2-Methyl-m-anisic acid - L18729 - Alfa Aesar

L18729 3-Methoxy-2-methylbenzoic acid, 97%

Codice CAS
55289-06-0
Sinonimi
3-Methoxy-o-toluic acid
2-Methyl-m-anisic acid

Dimensioni Prezzo ($) Quantità Disponibilità
10g 46,14
50g 116,00
Aggiungi al carrello Aggiungi al preventivo generale Visualizza articolo

3-Methoxy-2-methylbenzoic acid, 97%

MDL
MFCD02094039

Proprietà chimiche

Formula
C9H10O3
Peso formula
166.18
Solubilità
Soluble in methanol. Insoluble in water.

Applicazioni

3-Methoxy-2-methylbenzoic acid is used as a Corey-Bakshi-Shibata oxazaborolidine catalyst for asymmetric reduction and asymmetric synthesis. It is used in the asymmetric reduction of prochiral ketones. Other applications include the enantioselective synthesis of α-hydroxy acids, α-amino acids, C2 symmetrical ferrocenyl diols and propargyl alcohols. It is also used in desymmetrizing reduction leading to (S)-4-hydroxycyclohexenone.

Note

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with oxidizing agents.

Letteratura

Thi-Huu Nguyen.; Nguyet Trang Thanh Chau.; Anne-Sophie Castanet.; Kim Phi Phung Nguyen.; Jacques Mortier. Toward a Better Understanding on the Mechanism of Ortholithiation. Tuning of Selectivities in the Metalation of meta-Anisic Acid by an Appropriate Choice of Base. J. Org. Chem. 2005, 7 (12), 2445-2448.

Yoshiaki Nakagawaa, , , Kazunari Hattoria, Chieka Minakuchia, Soichi Kugimiyaa, Tamio Ueno. Relationships between structure and molting hormonal activity of tebufenozide, methoxyfenozide, and their analogs in cultured integument system of Chilo suppressalis Walker. Steroids. 2000, 65 (3), 117-123.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Beilstein
510395
Codice tariffe armonizzato
2918.99
TSCA
No

Raccomandato

  • H50227

    3-Ethoxybenzoyl chloride, 98%
  • L07337

    1,4-Cyclohexadiene, 97% stab. with 0.1% BHT

Visualizzati di recente

Prodotti chimici

Scienze della vita

Metalli e materiali

Catalizzatori

Apparecchiature di analisi e di laboratorio