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Methyl nitroacetate is used in the synthesis of aromatic and heteroaromatic linear (E)-alfa-nitro-arylpentenoates. It is also used to prepare phenyliodonium ylide. Further, it is utilized in the highly enantioselective and diastereoselective copper(I)-catalyzed cyclopropanation of alkenes. In addition to this, it is employed in the production of methyl (Z)-2-nitro-3-(4-nitrophenyl)-2-propenoate through reaction with 4-nitrobenzylideneaniline.
Hoffmann, R. C.; Schneider, J. J. Synergistic and Antagonistic Ligand Effects in the Transformation of Silver Compounds of Keto- and Cyano-Functionalised Oximates and Nitronates: A Systematic Study Using Thermal Analysis. Eur. J. Inorg. Chem. 2015, 2015 (25), 4254-4259.
Afreh, I.; Wujcik, E. K.; Blasdel, N.; Sauer, B.; Kaya, S.; Duirk, S.; Monty, C. N. Detection of halogenated organics by their inhibitory action in a catalytic reaction between dimethyl acetylenedicarboxylate and 2-methyl-4-nitroaniline. J. Anal. Chem. 2015, 70 (7), 825-830.
Dichiarazioni di rischio (UE): H303-H315-H319-H335
May be harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Dichiarazioni precauzionali: P260-P201-P280g-P304+P340-P405-P501a
Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.