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4187-56-8 - (S)-(-)-1-(4-Chlorophenyl)ethylamine, ChiPros® 97%, ee 98% - (S)-4-Chloro-alpha-methylbenzylamine - ClophaS - L19052 - Alfa Aesar

L19052 (S)-(-)-1-(4-Chlorophenyl)ethylamine, ChiPros® 97%, ee 98%

Codice CAS
4187-56-8
Sinonimi
(S)-4-Chloro-alpha-methylbenzylamine
ClophaS

Dimensioni Prezzo ($) Quantità Disponibilità
1g 35,10
5g 87,93
25g 288,80
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(S)-(-)-1-(4-Chlorophenyl)ethylamine, ChiPros® 97%, ee 98%

MDL
MFCD00671640

Proprietà chimiche

Formula
C8H10ClN
Peso formula
155.63
Punto di ebollizione
232°
Punto di infiammabilità
115°(239°F)
Densità
1.110
Indice di rifrazione
1.5418
Sensibilità
Air Sensitive
Solubilità
Soluble in water at 25°C 11 g/L.

Applicazioni

It is used as a substrate in palladium catalysts on alkaline-earth supports for racemization and dynamic kinetic resolution of benzylic amines.

Note

Air sensitive. Store away from acids, air, acid chlorides, acid anhydrides and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas.

Letteratura

R. Jansen, et al. Structural Similarity and Its Surprises:? Endothelin Receptor Antagonists - Process Research and Development Report.Org. Proc. Res. Dev.,2001,5(1), 16-22.

Sandra Reemers, et al. Cobalt complexes derived from chiral quasi-racemic ligands as building blocks for binary crystals.Inorg. Chem. Commun.,2002,5(10), 829-831.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H301-H330-H314-H318-H411-H401

Toxic if swallowed. Fatal if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. Toxic to aquatic life with long lasting effects. Toxic to aquatic life.

Dichiarazioni precauzionali: P260-P284-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P320-P330-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear respiratory protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment is urgent (see label). Rinse mouth. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Beilstein
2412316
Classe di rischio
8
Gruppo di imballaggio
III
Codice tariffe armonizzato
2921.49
TSCA
No

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