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133407-38-2 - (R)-(+)-N-Methoxymethyl-N-(trimethylsilyl)methyl-1-phenylethylamine, tech. 85% - L19413 - Alfa Aesar

L19413 (R)-(+)-N-Methoxymethyl-N-(trimethylsilyl)methyl-1-phenylethylamine, tech. 85%

Codice CAS
133407-38-2
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
1g 63,36
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(R)-(+)-N-Methoxymethyl-N-(trimethylsilyl)methyl-1-phenylethylamine, tech. 85%

MDL
MFCD06798959

Proprietà chimiche

Formula
C14H25NOSi
Peso formula
251.45
Punto di ebollizione
82-84°/0.2mm
Densità
0.926
Indice di rifrazione
1.4930
Sensibilità
Moisture Sensitive
Solubilità
Not miscible or difficult to mix in water.

Applicazioni

(R)-(+)-N-Methoxymethyl-N-(trimethylsilyl)methyl-1-phenylethylamine ligand is commonly used in the synthesis of organometallic catalysts and for many applications, such as asymmetric hydrogenation, asymmetric hydroboration, coupling reactions, addition reactions and reductions reactions.

Note

Store under inert gas. It is sensitive to moisture. Store in a cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.

Letteratura

Andrew H. Fray.; A. I. Meyers. Single and Double Diastereoselection in Azomethine Ylide Cycloaddition Reactions with Unsaturated Chiral Bicyclic Lactams. J. Org. Chem. 1996, 61 (10), 3362-3374.

The azomethine ylide, from the reaction with TFA in DCM, showed high facial selectivity in additions to chiral unsaturated bicyclic lactams: J. Org. Chem., 61, 3362 (1996).

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Beilstein
4745464
Codice tariffe armonizzato
2931.90
TSCA
No

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