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73852-17-2 - 2,6-Dichlorobenzeneboronic acid, 95% - 2,6-Dichlorophenylboronic acid - L19816 - Alfa Aesar

L19816 2,6-Dichlorobenzeneboronic acid, 95%

Codice CAS
73852-17-2
Sinonimi
2,6-Dichlorophenylboronic acid

Dimensioni Prezzo ($) Quantità Disponibilità
250mg 47,28
1g 146,26
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2,6-Dichlorobenzeneboronic acid, 95%

MDL
MFCD00064869
EINECS
000-000-0

Proprietà chimiche

Formula
C6H5BCl2O2
Peso formula
190.82
Punto di fusione
151-152°
Solubilità
Insoluble in water.

Applicazioni

Reagent used for palladium-catalyzed stille and suzuki-miyaura cross-couplings, palladium (pd)-catalytized reactions. Reagent used in preparation of common building blocks for pharmaceuticals and agrochemicals.

Note

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Letteratura

Ben W Glasspoole et. al. Suzuki-Miyaura cross-couplings of secondary allylic boronic esters.. Chemical Communications. 2012, 48 (9), 1230-1232 .

Fernandes, R. R.; et al.Oxadiazoline and Ketoimine Palladium(II) Complexes as Highly Efficient Catalysts for Suzuki-Miyaura Cross-Coupling Reactions in Supercritical Carbon Dioxide. Adv. Synth. Catal. 2012, 353 1153-1160.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Beilstein
4802506
Codice tariffe armonizzato
2931.90
TSCA
No

Raccomandato

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