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5315-25-3 - 2-Bromo-6-methylpyridine, 98% - 6-Bromo-2-picoline - L20018 - Alfa Aesar

L20018 2-Bromo-6-methylpyridine, 98%

Codice CAS
5315-25-3
Sinonimi
6-Bromo-2-picoline

Dimensioni Prezzo ($) Quantità Disponibilità
5g 63,76
25g 264,71
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2-Bromo-6-methylpyridine, 98%

MDL
MFCD00040743
EINECS
226-173-4

Proprietà chimiche

Formula
C6H6BrN
Peso formula
172.03
Punto di ebollizione
102-103°/20mm
Punto di infiammabilità
97°(206°F)
Densità
1.512
Indice di rifrazione
1.5625
Solubilità
Soluble in chloroform, ethyl aceate. Not miscible or difficult to mix with water.

Applicazioni

6-Bromo-2-picoline is a halogenated pyridine derivative used is a building block in the preparation of nitrogen containing heterocyclic compounds. It may used in following synthesis 6,6?-dimethyl-2,2?-bipyridine, 6-methyl-2-pyridyl-2-pyridylmethanone, 2-methyl-6-(trimethylsilyl)-pyridine and N,N’-bis-(6-methylpyrid-2-yl)-(1R,2R)-1,2- diaminocyclohexane (cydiampy).

Note

Store in cool, dry place in tightly closed container. With adequate ventilation. Store away from oxidizing agent.

Letteratura

Rajalakshmanan E and Alexander V. Synthesis of Dimethylbipyridines by the Reductive Coupling of 2-Halomethylpyridines with Nickel Catalyst. Synth. Commun. 2005,35(6), 891-895.

Abarca B, et al. 3-(2-Pyridyl)-[1,2,3] triazolo [1,5-a] pyridines. An experimental and theoretical (DFT) study of the ring-chain isomerization. Org. Biomol. Chem. 2005,3(21), 3905-3910.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H301-H311-H332-H315-H319

Toxic if swallowed. Toxic in contact with skin. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation.

Dichiarazioni precauzionali: P261-P280-P301+P310-P305+P351+P338-P361-P304+P340-P362-P312-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Remove/Take off immediately all contaminated clothing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Beilstein
107322
Codice tariffe armonizzato
2933.39
TSCA
No

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