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Propargyl chloride may be used as propargylating agent in the preparation of arabinogalactan propargyl ethers with degree of substitution up to 1.8. It may be used for the in situ preparation of propargyltrichlorosilane and allenyltrichlorosilane, required for the synthesis of optically active allenic and homopropargylic alcohols. Propargyl chloride solution may be used for the enantioselective synthesis of enantiomerically enriched homopropargyl alcohols.
Lyudmila A. Grischenko; Lidiya N. Parshina; Lyudmila V. Kanitskaya; Lyudmila I. Larina; Lyubov N. Novikova; Boris A. Trofimov. Propargylation of arabinogalactan with propargyl halidesa facile route to new functionalized biopolymers. Carbohydrate Research. 2013, 376 7-14.
Nakajima M, et al. Selective synthesis of optically active allenic and homopropargylic alcohols from propargyl chloride. Tetrahedron Asymmetry. 2002, 12 (22), 2449-52.
Dichiarazioni di rischio (UE): H225-H301-H311-H331-H314-H318-H361-H336-H373-H304
Highly flammable liquid and vapour. Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. Suspected of damaging fertility or the unborn child. May cause drowsiness or dizziness. May cause damage to organs through prolonged or repeated exposure. May be fatal if swallowed and enters airways.
Dichiarazioni precauzionali: P210-P301+P310a-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF SWALLOWED: Immediately call a POISON CENTER/doctor IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.