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87-85-4 - Hexamethylbenzene, 99+% - Mellitene - A10294 - Alfa Aesar

A10294 Hexamethylbenzene, 99+%

CAS 번호
87-85-4
동의어
Mellitene

사이즈 가격 ($) 수량 재고 여부
1g 21.00
5g 59.10
25g 182.00
장바구니에 추가 대량 견적에 추가 항목 보기

Hexamethylbenzene, 99+%

MDL
MFCD00008523
EINECS
201-777-0

화학적 특성

화학식
C12H18
화학 식량
162.28
융점
163-167°
비등점
265°
밀도
1.063
용해도
Insoluble in water

용도

Hexamethylbenzene is used as pharmaceutical intermediates, in organic synthesis of compounds, as a solvent for He-NMR spectroscopy. Used as a ligand in organometallic chemistry. Reaction with dimethyldioxirane, gives the major product, an unusual oxepane triepoxide.

참고

Incompatible with nitromethane, strong oxidizing agents.

참조 문헌

Helena L. Chum; V. R. Koch; L. L. Miller; R. A. Osteryoung. Electrochemical scrutiny of organometallic iron complexes and hexamethylbenzene in a room temperature molten salt. J. Am. Chem. Soc.1975, 97 (11), 3264-3265.

Oxidative rearrangement occurs on treatment with peroxytrifluoroacetic acid (caution! 90% H2O2) and BF3 etherate to give hexamethyl-2,4-cyclohexadienone: J. Am. Chem. Soc., 88, 1005 (1966); Org. Synth. Coll., 5, 598 (1973). Reaction with dimethyldioxirane, on the other hand, gives, as the major product, an unusual oxepane triepoxide: J. Org. Chem., 61, 7660 (1996):

기타 참조

바일슈타인
1905834
통합 관세 코드
2902.90
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
DA3200000

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