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104-53-0 - 3-Phenylpropionaldehyde, 95% - Hydrocinnamaldehyde - 3-Phenylpropanal - A10367 - Alfa Aesar

A10367 3-Phenylpropionaldehyde, 95%

CAS 번호
104-53-0
동의어
Hydrocinnamaldehyde
3-Phenylpropanal

사이즈 가격 ($) 수량 재고 여부
50g 35.40
250g 140.00
1000g 468.00
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3-Phenylpropionaldehyde, 95%

MDL
MFCD00007021
EINECS
203-211-8

화학적 특성

화학식
C9H10O
화학 식량
134.18
융점
-42°
비등점
222-223°
인화점
95°(203°F)
밀도
1.017
굴절률
1.5230
감도
Air Sensitive
용해도
Miscible with chloroform, dichloromethane, ethyl acetate, alcohol and ether. Immiscible with water.

용도

3-Phenylpropionaldehyde is used as a flavoring agent. It is also used in the preparation of cinnamaldehyde, 2-chloro hydrocinnamaldehyde by alfa chlorination and mixture of homopropargyl alcohols. It serves as a precursor for the synthesis of mixture of syn- and anti-beta-hydroxyallylsilanes by hydroboration of allenylsilane. It is also involved in the catalytic asymmetric cyanosilylation to prepare (2S)-2-hydroxy-4-phenylbutanenitrile. Further, it undergoes Henry reaction to form nitroaldols by reacting with nitromethane.

참고

Incompatible with strong oxidizing agents and strong bases.

참조 문헌

Durndell, L. J.; Wilson, K.; Lee, A. F. Platinum-catalysed cinnamaldehyde hydrogenation in continuous flow. RSC Adv. 2015, 5 (97), 80022-80026.

Kashyap, B.; Phukan, P. CuI catalyzed Barbier type allylation of aldehyde in presence of S1,S2-dipyridin-2-yl ferrocene-1,1'-dicarbothioate as ligand. Indian J. Chem. 2015, 54, 662-670.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

주의 설명서: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

바일슈타인
1071910
통합 관세 코드
2912.29
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
MW4890000

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