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105-36-2 - Ethyl bromoacetate, 98% - Bromoacetic acid ethyl ester - A10448 - Alfa Aesar

A10448 Ethyl bromoacetate, 98%

CAS 번호
105-36-2
동의어
Bromoacetic acid ethyl ester

사이즈 가격 ($) 수량 재고 여부
100g 30.80
500g 85.70
2500g 302.00
장바구니에 추가 대량 견적에 추가 항목 보기

Ethyl bromoacetate, 98%

MDL
MFCD00000191
EINECS
203-290-9

화학적 특성

화학식
C4H7BrO2
화학 식량
167.00
융점
-38°
비등점
159°
인화점
47°(117°F)
밀도
1.506
굴절률
1.4510
용해도
Miscible with ethanol, acetone, benzene and ethyl ether. Immiscible with water.

용도

Ethyl bromoacetate is widely used as an alkylating reagent involved in the Reformatsky reaction to prepare the beta-hydroxy esters by reacting with carbonyl compounds. It is also used for the syntheses of witting reagent, artificial diethylstilbestrol antigen, 3-phenyl-1-naphthol and steroidal thiazolidinone derivatives. It finds applications in the preparation of reversibly photoresponsive coumarin-stabilized polymeric nanoparticles in an aqueous medium which act as a detectable drug carrier.

참고

It is a lachrymator. Incompatible with strong oxidizing agents.

참조 문헌

Zhang, Y.; Zhao, K. T.; Fox, S. G.; Kim, J.; Kirsch, D. R.; Ferrante, R. J.; Silverman, R. B. Tertiary amine pyrazolones and their salts as inhibitors of mutant superoxide dismutase 1-dependent protein aggregation for the treatment of amyotrophic lateral sclerosis. J. Med. Chem. 2015, 58 (15), 5942-5949.

Grzybowski, M., & Gryko, D. T. Diketopyrrolopyrroles: Synthesis, Reactivity, and Optical Properties. Adv. Opt. Mater. 2015, 3 (3), 280-320.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H226-H300-H310-H330

Flammable liquid and vapour. Fatal if swallowed. Fatal in contact with skin. Fatal if inhaled.

주의 설명서: P301+P310a-P303+P361+P353-P304+P340-P320-P330-P405-P501a

IF SWALLOWED: Immediately call a POISON CENTER/doctor IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Specific treatment is urgent (see label). Rinse mouth. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

위험 등급
6.1
포장 그룹
II
통합 관세 코드
2915.90
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
AF6000000

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