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108-48-5 - 2,6-Lutidine, 98+% - 2,6-Dimethylpyridine - A10478 - Alfa Aesar

A10478 2,6-Lutidine, 98+%

CAS 번호
108-48-5
동의어
2,6-Dimethylpyridine

사이즈 가격 ($) 수량 재고 여부
25ml 16.20
100ml 26.40
500ml 72.40
장바구니에 추가 대량 견적에 추가 항목 보기

2,6-Lutidine, 98+%

MDL
MFCD00006345
EINECS
203-587-3

화학적 특성

화학식
C7H9N
화학 식량
107.16
융점
-7°
비등점
143-145°
인화점
33°(91°F)
밀도
0.923
굴절률
1.4970
감도
Hygroscopic
용해도
Miscible with water.

용도

2,6-Lutidine is used as a solvent in organic synthesis and as a sterically hindered mild base. It is also used as a vulcanization accelerator for dyes, resins and rubber. It also acts as a food additive.

참고

Incompatible with acids, acid chlorides, oxidizing agents and chloroformates.

참조 문헌

This hindered base has been recommended for the exhaustive methylation of aromatic amines: J. Org. Chem., 35, 1558 (1970), and for the Rosenmund reduction of acyl halides to aldehydes: Synthesis, 767 (1976).

Base catalyst for the silylation of highly-hindered secondary or tertiary alcohols by tert-Butyl­dimethyl­silyl­ trifluoromethanesulfonate, A12174.

For monometallation with potassium amide in liquid ammonia, and subsequent carboethoxylation with diethyl carbonate, see: Org. Synth. Coll., 6, 611 (1988).

/

Timmiatia, S. N.; Jalila, A. A.; Triwahyono, S.; Setiabudi, H. D.; Annuar, N. H. R. Formation of acidic Brönsted (MoOx)-(Hy)+ evidenced by XRD and 2,6-lutidine FTIR spectroscopy for cumene cracking. Appl. Catal., A2013, 459, 8-16.

Geoghegan, K.; Bode, J. W. Bespoke SnAP Reagents for the Synthesis of C-Substituted Spirocyclic and Bicyclic Saturated N-Heterocycles. Org. Lett. 2015, 17 (8), 1934-1937.

Hanson, S. K.; Baker, R. T. Knocking on Wood: Base Metal Complexes as Catalysts for Selective Oxidation of Lignin Models and Extracts. Acc. Chem. Res. 2015,48 (7), 2037-2048.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H226-H302-H315-H319-H335

Flammable liquid and vapour. Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

주의 설명서: P280h-P305+P351+P338

Wear protective gloves/clothing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

기타 참조

Merck
14,5616
바일슈타인
105690
위험 등급
3
포장 그룹
III
통합 관세 코드
2933.39
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
OK9700000

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