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55-21-0 - Benzamide, 98+% - A10501 - Alfa Aesar

A10501 Benzamide, 98+%

CAS 번호
55-21-0
동의어

사이즈 가격 ($) 수량 재고 여부
100g 26.20
500g 70.10
2500g 268.00
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Benzamide, 98+%

MDL
MFCD00007968
EINECS
200-227-7

화학적 특성

화학식
C7H7NO
화학 식량
121.14
융점
125-129°
비등점
288°
인화점
180°(356°F)
밀도
1.341
용해도
Soluble in water, methanol, ammonia, pyridine, carbon tetrachloride, carbon disulfide and ethanol. Slightly soluble in benzene and ethyl ether.

용도

Benzamide is utilized to study the mechanism of photocatalytic decomposition of aqueous solution of acetic acid, acetamide and acetonitrile in the presence of semiconductors. It is used as a nictoinamide-mimic PARP inhibitor and neuroprotectant. Further, it is used to develop a robust screening method to study biotransformations using (+)-gamma-lactamase enzyme. It is also employed in the determination of glycine. In addition to this, it is used as an intermediate in organic synthesis as well as in the production of pharmaceuticals and dyes.

참고

Incompatible with strong oxidizing agents and strong bases.

참조 문헌

Reduction with lithium aluminum hydride gives benzylamine. By using lithium tris(diethylamino)aluminum hydride (see Diethyl­amine, A11716), selective reduction to benzaldehyde is possible: Tetrahedron Lett., 32, 6903 (1991).

An exceptionally mild method for dehydration of amides to nitriles by transamidation with acetonitrile in the presence of an aldehyde and formic acid is exemplified by the high yield conversion of benzamide to benzonitrile: J. Org. Chem., 61, 6486 (1996).

Barrett, K. T.; Miller, S. J. Regioselective Derivatizations of a Tribrominated Atropisomeric Benzamide Scaffold. Org. Lett. 2015, 17 (3), 580-583.

Manna, S.; Antonchick, A. P. Organocatalytic Oxidative Annulation of Benzamide Derivatives with Alkynes. Angew. Chem. Int. Ed. 2014, 53 (28), 7324-7327.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H302-H341

Harmful if swallowed. Suspected of causing genetic defects.

주의 설명서: P201-P280-P301+P312a-P308+P313-P405-P501a

Obtain special instructions before use. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. IF exposed or concerned: Get medical advice/attention. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

Merck
14,1060
바일슈타인
385876
통합 관세 코드
2924.29
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
CU8700000

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