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127-06-0 - Acetone oxime, 98% - Acetoxime - 2-Propanone oxime - A10802 - Alfa Aesar

A10802 Acetone oxime, 98%

CAS 번호
127-06-0
동의어
Acetoxime
2-Propanone oxime

사이즈 가격 ($) 수량 재고 여부
50g 22.40
250g 65.70
1000g 225.00
장바구니에 추가 대량 견적에 추가 항목 보기

Acetone oxime, 98%

MDL
MFCD00002118
EINECS
204-820-1

화학적 특성

화학식
C3H7NO
화학 식량
73.10
융점
60-63°
비등점
133-135°
인화점
60°(140°F)
밀도
0.901
용해도
Soluble in water (330 g/L at 20°C).

용도

It is an intermediate used in organic synthesis and in agriculture. It is also an important raw material.

참고

Store away from oxidizing agents. Protect against electrostatic charges.

참조 문헌

Jianjun Wu.; Sarah C. Larsen. Solid-State Nuclear Magnetic Resonance Study of Acetone Oxime Adsorbed on CuZSM-5 and on HZSM-5. Journal of Catalysis. 1999, 182, (1), 244-256.

Karl Sohlberg.; Scott P. Leary.; Noel L. Owen.; Boris A. Trofimov. The infrared spectrum and conformation of acetone oxime vinyl ether. Vibrational Spectroscopy. 1997, 13, (2), 227-234.

Aldehydes and ketones can be converted to their oximes in high yield by an exchange process involving heating with acetone oxime in acetic acid at 110o: J. Prakt. Chem., 331, 870 (1989).

N-Protected form of hydroxylamine. For O-alkylation with sodium bromoacetate, and acid hydrolysis to O-carboxymethylhydroxylamine hydrochloride, see: Org. Synth. Coll., 3, 172 (1955).

For use of this and other simple oximes in the formation, by DCC-coupling, of active esters of N-protected oligopeptides, which react with C-protected amino acids to give peptides in high yield, see: Chem. Pharm. Bull., 17, 2937 (1969). See Appendix 6.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H228

Flammable solid.

주의 설명서: P210-P280a-P240-P241-P370+P378a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves and eye/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. In case of fire: Use for extinction: CO2, powder or water spray.

기타 참조

Merck
14,75
바일슈타인
1560146
위험 등급
4.1
포장 그룹
III
통합 관세 코드
2928.00
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
AL6825000

권장

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화학물질

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