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79-24-3 - Nitroethane, 99% - A10855 - Alfa Aesar

A10855 Nitroethane, 99%

CAS 번호
79-24-3
동의어

사이즈 가격 ($) 수량 재고 여부
100g 25.40
500g 53.90
장바구니에 추가 대량 견적에 추가 항목 보기

Nitroethane, 99%

MDL
MFCD00007404
EINECS
201-188-9

화학적 특성

화학식
CH3CH2NO2
화학 식량
75.07
융점
-89°
비등점
112-115°
인화점
30°(86°F)
밀도
1.046
굴절률
1.3920
용해도
Soluble in water (4.6 g/100 ml at 20°C).

용도

Nitroethane is used as industrial solvents and pharmaceutical intermediates, explosives and as rocket fuel.

참고

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. It is hygroscopic in nature. Incompatible with oxidizing agents, strong reducing agents, strong acids and strong bases.

참조 문헌

David J. T. Porters.; Harold J. Bright. Mechanism of Oxidation of Nitroethane by Glucose Oxidase. The Journal Of Biological Chemistry. 1977, 252, (12), 4361-4370.

Syun-ichi Kiyooka.; Yuichi Kaneko.; Ken-ichi Kume. The catalytic asymmetric aldol reaction of silyl ketene acetals with aldehydes in the presence of a chiral borane complex. Nitroethane as a highly effective solvent for catalytic conditions. Tetrahedron Letters. 1992, 33, (34), 4927-4930.

Aldehydes are converted to nitriles in one step in the presence of NaOAc/AcOH (NH4OAc gives the "expected" alkylidene derivative): Synthesis, 510 (1985):

For a review of the use of nitro-compounds as alkyl anion synthons, including methods for removing the nitro-group from the resulting carbon skeletons, see: Synthesis, 833 (1988).

For further reactions of aliphatic nitro-compounds, see Nitromethane, A11806.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H226-H302-H332

Flammable liquid and vapour. Harmful if swallowed. Harmful if inhaled.

주의 설명서: P210-P261-P280a-P303+P361+P353-P304+P340-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

Merck
14,6597
바일슈타인
1209324
위험 등급
3
포장 그룹
III
통합 관세 코드
2904.20
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
KI5600000

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