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105-50-0 - Diethyl acetone-1,3-dicarboxylate, 96% - Acetone-1,3-dicarboxylic acid diethyl ester - Diethyl 3-oxoglutarate - A10933 - Alfa Aesar

A10933 Diethyl acetone-1,3-dicarboxylate, 96%

CAS 번호
105-50-0
동의어
Acetone-1,3-dicarboxylic acid diethyl ester
Diethyl 3-oxoglutarate

사이즈 가격 ($) 수량 재고 여부
50g 38.70
250g 164.00
장바구니에 추가 대량 견적에 추가 항목 보기

Diethyl acetone-1,3-dicarboxylate, 96%

MDL
MFCD00009200
EINECS
203-302-2

화학적 특성

화학식
C9H14O5
화학 식량
202.21
비등점
134-135°/10mm
인화점
86°(186°F)
밀도
1.113
굴절률
1.4400
용해도
Insoluble in water and soluble in alcohol, ester, benzene.

용도

Synthesis of 1-substituted 4-ethoxycarbonyl-5- (ethoxycarbonylmethyl) pyrazoles Diethyl acetone-1, 3-dicarboxylate reacts with N, N-dimethylforma- mide dimethyl acetal (DMFDMA) in ethanol at room temperature. Unexpected product dichotomy is produced in the Biginelli-like condensation of 2-hydroxybenzaldehyde with urea or thiourea and dimethyl or diethyl acetone-1,3-dicarboxylate, respectively, as active methylene components. Ethyl 2-amino-4-(2-ethoxy-2-oxoethyl)thiazole-5-carboxylate (2a), prepared from diethylacetone-1,3-dicarboxylate, sulfuryl chloride and thiourea. Synthesis of diethyl 2,2-diethyl-3,5-dioxopimelate by the reaction of ethyl 3-chloro-3-oxo-2,2-dimethylpropionate with diethyl acetone-1,3-dicarboxylate.

참고

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

참조 문헌

T. A. Bryson,; T. M. Dolak. Dimethyl 2,3-Pentadienedioate. Organic Syntheses. <

Stefanie Reima,; Van Thi Hong Nguyen,; Uwe Albrechta,; Peter Langer. Synthesis of 3,5-dioxoalkanoates, 3,5-dioxopimelates and 2,4-dioxoadipates by acylation of 1,3-bis-silyl enol ethers. Tetrahedron Letters. 2005, 46 (48),8423-8425.

Valuable synthetic building block, compare Dimethyl­ acetone-1,3-dicarboxyl­ate, A14969. Used in synthesis of isoquinolin-2-ones: Heterocycles, 33, 515 (1992).

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H227

Combustible liquid.

주의 설명서: P210u-P280a-P370+P378a-P403+P235-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves and eye/face protection. In case of fire: Use for extinction: CO2, powder or water spray. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

바일슈타인
640146
통합 관세 코드
2918.30
TSCA(독성물질규제법)"
Yes

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