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3433-80-5 - 2-Bromobenzyl bromide, 98% - alpha,2-Dibromotoluene - A11285 - Alfa Aesar

A11285 2-Bromobenzyl bromide, 98%

CAS 번호
3433-80-5
동의어
alpha,2-Dibromotoluene

사이즈 가격 ($) 수량 재고 여부
10g 41.30
50g 117.00
장바구니에 추가 대량 견적에 추가 항목 보기

2-Bromobenzyl bromide, 98%

MDL
MFCD00000173
EINECS
222-334-8

화학적 특성

화학식
C7H6Br2
화학 식량
249.94
융점
29-32°
비등점
127-129°/19mm
인화점
>110°(230°F)
굴절률
1.6190
용해도
Insoluble in water.

용도

2-Bromobenzyl bromide was used in the synthesis of substituted quinazolines and 1,2,3,4-tetrahydroquinazolines, 2- and 3-substituted indenes, tris-2-bromotribenzylamine3.

참고

Store away from strong bases and oxidizing agents. Incompatible with amines, alcohols, steel.

참조 문헌

Ronald L. Halterman; Chengian Zhu. Efficient synthesis of 2- and 3-substituted indenes from 2-bromobenzyl bromide through an enolate alkylation/Cr(II)/Ni(II)-mediated carbonyl addition sequence. Tetrahedron letters 1999, 40, 7445-7448.

Yao Dai; Xiujuan Feng; Hesong Liu; Hua Jiang and Ming Bao. Synthesis of 2-Naphthols via Carbonylative Stille Coupling Reaction of 2-Bromobenzyl Bromides with Tributylallylstannane Followed by the Heck Reaction. J. Org. Chem.2011, 76, (24)10068-10077.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

주의 설명서: P260u-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

바일슈타인
971015
위험 등급
8
포장 그룹
II
통합 관세 코드
2903.99
TSCA(독성물질규제법)"
Yes

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