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110-83-8 - Cyclohexene, 99% - A11359 - Alfa Aesar

A11359 Cyclohexene, 99%

CAS 번호
110-83-8
동의어

사이즈 가격 ($) 수량 재고 여부
100ml 19.10
500ml 27.90
2500ml 117.00
장바구니에 추가 대량 견적에 추가 항목 보기

Cyclohexene, 99%

MDL
MFCD00001539
EINECS
203-807-8

화학적 특성

화학식
C6H10
화학 식량
82.15
융점
-104°
비등점
83-85°
인화점
-20°(-4°F)
밀도
0.811
굴절률
1.4460
용해도
Immiscible with cold water.

용도

Cyclohexene is used as a solvent. It is employed as a precursor to caprolactam, adipic acid, maleic acid, dicyclohexyladipate and cyclohexeneoxide. It is used as an intermediate for the production of cyclohexanol and cyclohexeneoxide.

참고

Incompatible with strong oxidizing agents.

참조 문헌

Protection of the phenolic OH of tyrosine as the cyclohexyl ether has been effected with BF3 etherate. The group can be cleaved with HF or HBr/AcOH: J. Am. Chem. Soc., 100, 3559 (1978).

Hydrogen donor in catalytic hydrogen-transfer reactions, usually with palladium. For reviews, see: Chem. Rev., 74, 567 (1974); 85, 129 (1985). Examples:

Hydrogenolysis of benzyloxycarbonyl groups: Synthesis, 685 (1976). Simultaneous cleavage of benzyl and benzyloxycarbonyl groups: J. Chem. Soc., Perkin 1, 490 (1977). Cleavage of benzyl ethers: Synthesis, 396 (1981). With FeCl3, reduction of aryl carbonyl groups to methylene: J. Chem. Soc., Chem. Commun., 757 (1976).

Conditions have been described for work-up of the ozonide to give the monoacetal of the dialdehyde, the aldehydo-ester, or the dimethyl acetal of the methyl ester: Org. Synth. Coll., 7, 168 (1990).

Undergoes allylic acetoxylation, catalyzed by Palladium(II)­ acetate, 10516 , in the presence of MnO2 and 1,4-benzoquinone: Org. Synth. Coll., 8, 137 (1993).

Xu, L. Q.; Chen, J. C.; Qian, S. S.; Zhang, A. K.; Fu, G. D.; Li, C. M.; Kang, E. T. PEGylated Metalloporphyrin Nanoparticles as a Promising Catalyst for the Heterogeneous Oxidation of Cyclohexene in Water. Macromol. Chem. Phys. 2015, 216 (4), 417-426.

Hu, X.; Shi, Y.; Zhang, Y.; Zhu, B.; Zhang, S.; Huang, W. Nanotubular TiO2-supported amorphous Co-B catalysts and their catalytic performances for hydroformylation of cyclohexene. Catal. Commun. 2015, 59, 45-49.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H225-H302-H304

Highly flammable liquid and vapour. Harmful if swallowed. May be fatal if swallowed and enters airways.

주의 설명서: P210-P280a-P301+P310a-P303+P361+P353-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves and eye/face protection. IF SWALLOWED: Immediately call a POISON CENTER/doctor IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

Merck
14,2727
바일슈타인
906737
위험 등급
3
포장 그룹
II
통합 관세 코드
2902.19
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
GW2500000

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