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108-86-1 - Bromobenzene, 99% - A11407 - Alfa Aesar

A11407 Bromobenzene, 99%

CAS 번호
108-86-1
동의어

사이즈 가격 ($) 수량 재고 여부
500g 30.10
2500g 99.30
10000g 311.00
장바구니에 추가 대량 견적에 추가 항목 보기

Bromobenzene, 99%

MDL
MFCD00000055
EINECS
203-623-8

화학적 특성

화학식
C6H5Br
화학 식량
157.02
융점
-31°
비등점
155-156°
인화점
51°(123°F)
밀도
1.492
굴절률
1.5590
용해도
Miscible with diethyl ether, alcohol, carbon tetrachloride, chloroform and benzene.

용도

Bromobenzene is used as solvent in organic synthesis. It is used to prepare the phenylmagnesium bromide, a Grignard reagent, an intermediate in the preparation of benzoic acid by reacting with carbon dioxide. It is a precursor for making phencyclidine. It is useful for the introduction of phenyl group through palladium-catalyzed coupling reactions viz. the Suzuki reaction.

참고

Store in cool place. Avoid inhalation of vapor or mist. Incompatible with strong oxidizing agents.

참조 문헌

Man, I. C.; Şoriga, Ş. G.; Pârvulescu, V. Theoretical study of the adsorption of bromobenzene and aniline on Cu2O(1 1 0):CuO and Cu2O(1 1 1):CuO surfaces. Chem. Phys. Lett. 2014, 604, 38-45.

Zhang, X.; Borjian, S.; Baird, M. C. An unusual product distribution from the reaction of Pd(η3-1-PhC3H4)(η5-C5H5) with a deficiency of PPh3 in the presence of bromobenzene. Transition Met. Chem. 2015, 40 (2), 125-129.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H226-H303-H315

Flammable liquid and vapour. May be harmful if swallowed. Causes skin irritation.

주의 설명서: P210-P280a-P240-P241-P303+P361+P353-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves and eye/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

Merck
14,1406
바일슈타인
1236661
위험 등급
3
포장 그룹
III
통합 관세 코드
2903.99
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
CY9000000

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