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1734-79-8 - 4-Nitrocinnamaldehyde, predominantly trans, 98% - A11467 - Alfa Aesar

A11467 4-Nitrocinnamaldehyde, predominantly trans, 98%

CAS 번호
1734-79-8
동의어

사이즈 가격 ($) 수량 재고 여부
5g 86.70
25g 354.00
50g 634.00
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4-Nitrocinnamaldehyde, predominantly trans, 98%

MDL
MFCD00007379
EINECS
217-076-8

화학적 특성

화학식
C9H7NO3
화학 식량
177.16
융점
138-142°
감도
Air Sensitive
용해도
Insoluble in water.

용도

Doebner-Miller reaction the 4- nitrocinnamaldehyde and 2-methylaniline in concentrated HC1 give the corresponding 8-methyl-2-phenylquinoline (3: R = 4'-N02) directly. The asymmetric Friedel-Crafts-type alkylation in aqueous media reaction of 4-Nitrocinnamaldehydr with N-methyl indole using trifluoroacetic acid (TFA) salt of the PEG-PS-supported prolyl peptide having the polyleucine tether as a catalyst. 4-Nitrocinnamaldehyde has been used in the preparation of 2, 2?-[(E)-3-(4-nitrophenyl) prop-2-ene-1,1-diyl] bis(3-hydroxy-5, 5-dimethylcyclohex-2-en-1-one).

참고

Air Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, air.

참조 문헌

Graham J. Atwell,; Bruce C. Baguley,; William A. Denny. Potential antitumor agents. 57. 2-Phenylquinoline-8-carboxamides as minimal DNA-intercalating antitumor agents with in vivo solid tumor activity . J. Med. Chem. 1989, 32(2),396-401.

Kengo Akagawa,; Takuhiro Yamashita,; Seiji Sakamoto,; Kazuaki Kudo. Friedel-Crafts-type alkylation in aqueous media using resin-supported peptide catalyst having polyleucine. Tetrahedron Letters. 2009, 50 (40) ,5602-5604.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

주의 설명서: P280g-P305+P351+P338

Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

기타 참조

바일슈타인
1565424
통합 관세 코드
2913.00
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
GD6650000

권장

  • A10293

    1,4-Dinitrobenzene, 98+%
  • A10308

    2-Nitrocinnamaldehyde, predominantly trans, 98%
  • A10429

    alpha-Methylcinnamaldehyde, predominantly (E), 97%
  • A11655

    4-Nitrobenzaldehyde, 99%
  • A12839

    trans-4-Methoxycinnamaldehyde, 98+%

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