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392-56-3 - Hexafluorobenzene, 99% - A11500 - Alfa Aesar

A11500 Hexafluorobenzene, 99%

CAS 번호
392-56-3
동의어

사이즈 가격 ($) 수량 재고 여부
10g 35.60
50g 120.00
250g 433.00
장바구니에 추가 대량 견적에 추가 항목 보기

Hexafluorobenzene, 99%

MDL
MFCD00000288
EINECS
206-876-2

화학적 특성

화학식
C6F6
화학 식량
186.06
융점
4-5°
비등점
80-81°
인화점
10°(50°F)
밀도
1.616
굴절률
1.3780
용해도
Immiscible with water.

용도

Hexafluorobenzene is used as a solvent in photochemical reactions. It is also used as a reference compound in fluorine-19 NMR, carbon-13 NMR. It is used as a solvent in proton NMR, IR spectrum and UV-spectra. It is used as anticorrosive, antifriction and anti-tumor agents. Further, it is used as a reference molecule to investigate tissue oxygenation in vivo studies. It forms series of 1:1 complexes with naphthalene, anthracene, phenanthrene, pyrene and triphenylene.

참고

Incompatible with strong oxidizing agents.

참조 문헌

Exchanges with Grignard reagents, under catalysis by CoCl2, to give the pentafluorophenyl Grignard reagent: J. Organomet. Chem., 19, 191 (1969).

Reacts with ethyl cyanoacetate, in the presence of K2CO3 in DMF, to displace one F atom, as the first step of a synthesis of pentafluorophenylacetonitrile: Org. Synth. Coll., 6, 873 (1988).

Gong, S.; Luo, Q.; Feng, X.; Li, Q.-s.; Xie, Y.; King, R. B.; Schaefer Iii, H. F. Triple decker sandwiches and related compounds of the first row transition metals with cyclopentadienyl and hexafluorobenzene rings: remarkable effects of fluorine substitution. Phys. Chem. Chem. Phys. 2015, 17 (31), 20100-20113.

Ma, W. C.; Tsai, C. Y.; Huang, C. Investigation of atmospheric-pressure plasma deposited hexafluorobenzene fluorocarbon film. Surf. Coat. Technol. 2014, 259, 290-296.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H225-H319

Highly flammable liquid and vapour. Causes serious eye irritation.

주의 설명서: P210-P243-P305+P351+P338

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Take precautionary measures against static discharge. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

기타 참조

Merck
14,4686
바일슈타인
1683438
위험 등급
3
포장 그룹
II
통합 관세 코드
2903.99
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
DA3050000

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