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789-25-3 - Triphenylsilane, 97% - Triphenylhydrosilane - 1,1',1''-Silylidynetrisbenzene - A11605 - Alfa Aesar

A11605 Triphenylsilane, 97%

CAS 번호
789-25-3
동의어
Triphenylhydrosilane
1,1',1''-Silylidynetrisbenzene

사이즈 가격 ($) 수량 재고 여부
10g 29.30
50g 94.80
장바구니에 추가 대량 견적에 추가 항목 보기

Triphenylsilane, 97%

MDL
MFCD00003003
EINECS
212-333-0

화학적 특성

화학식
(C6H5)3SiH
화학 식량
260.41
융점
42-44°
비등점
159-163°/3mm
인화점
76°(169°F)
감도
Moisture Sensitive
용해도
Soluble in methanol. Decomposes in water.

용도

Triphenylsilane acts as a reactant or reagent for catalytic hydrogen deuterium exchange reactions of silanes, to be oxidized by carbon nanotube-gold nanohybrids, for hydrolysis by ruthenium complexes, for hydrosilylation to produce enolsilanes, for synthesis of bromosilanes, for ozone oxidation of silyl-alkenes for synthesis of α-O-silylated acyloin derivatives. It is used to synthesize hydrido silyl and bis(silyl) bis(imidazolinylidene) nickel complexes.

참고

Air Sensitive. Incompatible with air and oxidizing agents.

참조 문헌

George C Fortman; Heiko Jacobsen; Luigi Cavallo; Steven P Nolan. Catalytic deuteration of silanes mediated by N-heterocyclic carbene-Ir(III) complexes. Chemical Communications.2011, 47 (34), 9723-9725.

Jubi John; Edmond Gravel; Agnès Hagège; Haiyan Li; Thierry Gacoin; Eric Doris. Catalytic oxidation of silanes by carbon nanotube-gold nanohybrids. Angewandte Chemie. International edition in English.2011, 50 (33), 7533-7536.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

주의 설명서: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

바일슈타인
978182
통합 관세 코드
2931.90
TSCA(독성물질규제법)"
Yes

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