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460-00-4 - 1-Bromo-4-fluorobenzene, 99% - 4-Bromofluorobenzene - A11630 - Alfa Aesar

A11630 1-Bromo-4-fluorobenzene, 99%

CAS 번호
460-00-4
동의어
4-Bromofluorobenzene

사이즈 가격 ($) 수량 재고 여부
100g 43.20
500g 130.00
2500g 510.00
장바구니에 추가 대량 견적에 추가 항목 보기

1-Bromo-4-fluorobenzene, 99%

MDL
MFCD00000342
EINECS
207-300-2

화학적 특성

화학식
C6H4BrF
화학 식량
175.01
융점
-16°
비등점
151-153°
인화점
60°(140°F)
밀도
1.604
굴절률
1.5270
용해도
Soluble in water(0.14g/L).

용도

1-Bromo-4-fluorobenzene is used as an intermediate in the synthesis of atypical antipsychotic agents.

참고

Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

참조 문헌

Xi-Bin Gu.; Guang-Jun Wang.; Jian-Hua Huang.; Ke-Li Han.; Guo-Zhong He.; Nan-Quan Lou. Photofragment Translational Spectroscopy of 1-Bromo-3-fluorobenzene and 1-Bromo-4-fluorobenzene at 266 nm. J. Phys. Chem. 2001, 105, (2), 354-362.

Kuniaki Kawataa.; Tsuyoshi Ibarakia.; Akiko Tanabea.; Hiroaki Yagoha.; Akiko Shinodab.; Hiroshi Suzukib.; Akio Yasuhara. Gas chromatographic-mass spectrometric determination of hydrophilic compounds in environmental water by solid-phase extraction with activated carbon fiber felt. Journal of Chromatography A. 2001, 911, (1), 75-83.

The Br undergoes selective displacement with Na alkoxides in NMP, in the presence of CuBr: Tetrahedron, 48, 3633 (1992).

Lithiation with LDA at -75o results mainly in deprotonation ortho to F; subsequent reaction with CO2 gives 5-bromo-2-fluorobenzoic acid: Tetrahedron Lett., 33, 7495 (1992). Improved yields are obtained by the use of Li 2,2,6,6-tetramethylpiperidide (LTMP) as base: Tetrahedron Lett., 37, 6551 (1996).

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H226-H332-H319

Flammable liquid and vapour. Harmful if inhaled. Causes serious eye irritation.

주의 설명서: P261-P305+P351+P338

Avoid breathing dust/fume/gas/mist/vapours/spray. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

기타 참조

바일슈타인
774102
위험 등급
3
포장 그룹
III
통합 관세 코드
2903.99
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
CY9033750

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