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383-67-5 - Allyl trifluoroacetate, 97% - Trifluoroacetic acid allyl ester - A11690 - Alfa Aesar

A11690 Allyl trifluoroacetate, 97%

CAS 번호
383-67-5
동의어
Trifluoroacetic acid allyl ester

사이즈 가격 ($) 수량 재고 여부
10g 30.70
50g 113.00
250g 433.00
장바구니에 추가 대량 견적에 추가 항목 보기

Allyl trifluoroacetate, 97%

MDL
MFCD00013567
EINECS
206-853-7

화학적 특성

화학식
CH2=CHCH2O2CCF3
화학 식량
154.09
비등점
73-75°
인화점
-1°(30°F)
밀도
1.183
굴절률
1.3360
용해도
Not miscible or difficult to mix with water.

용도

Used as nucleophilic ally metal precursor in alkylation reaction that generates homoallylic amines. Also used as chemical reagent and intermediate for pharmaceutical.

참고

Store in cool, dry conditions in well sealed container. Store away from oxidizing agent.

참조 문헌

Robin E. Grote; and Elizabeth R. Jarvo. Palladium-Catalyzed, One-Pot, Three-Component Synthesis of Homoallylic Amines from Aldehydes, Anisidine, and Allyl Trifluoroacetate. Org. Lett. 2009, 11 (2), 485-488.

Debby de Groot; Janine C. de Wilde; Richard J. van Haaren; Joost N. H. Reek; Paul C. J. Kamer; Piet W. N. M. van Leeuwen; Eva B. Eggeling; Dieter Vogt; Huub Kooijman; Anthony L. Spek and Alexander W. van der Made . Palladium complexes of phosphine functionalised carbosilane dendrimers as catalysts in a continuous flow membrane reactor. Chem. Commun. 1999, (17), 1623-1624.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H225-H314-H318

Highly flammable liquid and vapour. Causes severe skin burns and eye damage. Causes serious eye damage.

주의 설명서: P210-P260u-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

바일슈타인
1766312
위험 등급
3
포장 그룹
II
통합 관세 코드
2915.90
TSCA(독성물질규제법)"
No

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