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106-95-6 - Allyl bromide, 99%, stab. with 300-1000ppm Propylene oxide - 3-Bromo-1-propene - A11766 - Alfa Aesar

A11766 Allyl bromide, 99%, stab. with 300-1000ppm Propylene oxide

CAS 번호
106-95-6
동의어
3-Bromo-1-propene

사이즈 가격 ($) 수량 재고 여부
250g 25.20
1000g 68.30
장바구니에 추가 대량 견적에 추가 항목 보기

Allyl bromide, 99%, stab. with 300-1000ppm Propylene oxide

MDL
MFCD00000244
EINECS
203-446-6

화학적 특성

화학식
C3H5Br
화학 식량
120.98
융점
-119°
비등점
70-71°
인화점
-2°(28°F)
밀도
1.398
굴절률
1.4700
감도
Light Sensitive
용해도
Slightly miscible with water.

용도

Allyl bromide is used as an alkylating agent in the synthesis of pharmaceuticals, polymers, adhesives, perfumes, biochemicals and other allylic compounds. It is used as precursor for the preparation of allyliczinc bromide by reacting it with zinc. It is also used in the preparation of allylethers like allyl decyl ether, allyl benzyl ether and allyl geranyl ether. It is also used in the preparation of R enantiomer of allyl phenyl carbinol (APC) such as 1-phenyl-3-butene, which is a valuable intermediate for drugs and agro-chemicals.

참고

Moisture and light sensitive. Incompatible with oxidizing agents, alkali metals, alkaline earth metals, amides, amines and powdered metals.

참조 문헌

Pandey, G.; Kant, R.; Batra, S. A general route to the synthesis of indoloazocines using allyl bromides prepared from Morita-Baylis-Hillman adducts. Tetrahedron Lett. 2015, 56 (7), 930-933.

Fananas-Mastral, M.; Vitale, R.; Perez, M.; Feringa, B. L. Enantioselective Synthesis of All-Carbon Quaternary Stereogenic Centers via Copper-Catalyzed Asymmetric Allylic Alkylation of (Z)-Allyl Bromides with Organolithium Reagents. Chem. Eur. J. 2015, 21 (11), 4209-4212.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H225-H301-H331-H314-H318-H340-H350

Highly flammable liquid and vapour. Toxic if swallowed. Toxic if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. May cause genetic defects. May cause cancer.

주의 설명서: P210-P301+P310a-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF SWALLOWED: Immediately call a POISON CENTER/doctor IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

Merck
14,288
위험 등급
3
포장 그룹
I
통합 관세 코드
2903.39
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
UC7090000

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