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694-80-4 - 1-Bromo-2-chlorobenzene, 98+% - 2-Bromochlorobenzene - A11782 - Alfa Aesar

A11782 1-Bromo-2-chlorobenzene, 98+%

CAS 번호
694-80-4
동의어
2-Bromochlorobenzene

사이즈 가격 ($) 수량 재고 여부
50g 51.20
250g 172.00
1000g 588.00
장바구니에 추가 대량 견적에 추가 항목 보기

1-Bromo-2-chlorobenzene, 98+%

MDL
MFCD00000532
EINECS
211-775-1

화학적 특성

화학식
C6H4BrCl
화학 식량
191.46
융점
-13°
비등점
203-205°
인화점
79°(174°F)
밀도
1.649
굴절률
1.5815
용해도
Immiscible with water.

용도

1-Bromo-2-chlorobenzene finds application in Gas Chromatography and Liquid Chromatography analysis. It is also used as an intermediate in pharmaceutical and synthetic chemistry. Further, it acts as a reagent in the preparation of arylpiperidines and aryltetrahydropyridines as 5-HT2C agonists.

참고

Store in a cool place. Incompatible with strong oxidizing agents.

참조 문헌

Lithiation with LDA occurs ortho to the chlorine atom; subsequent reaction with electrophiles provides access to mixed dihalo derivatives such as 3-bromo-2-chlorobenzoic acid: Tetrahedron Lett., 36, 881 (1995).

Chen, J.; Natte, K.; Wu, X. F. Convenient palladium-catalyzed carbonylative synthesis of caprolactam and butyrolactam derived phthalimides and amides by using DBU and DBN as the nitrogen source. Tetrahedron Lett. 2015, 56 (2), 342-345.

Gao, J.; Zhu, J.; Chen, L.; Shao, Y.; Zhu, J.; Huang, Y.; Wang, X.; Lv, X. Synthesis of benzimidazo[2,1-b]benzothiazole derivatives through sequential Cu-catalyzed domino coupling and Pd-catalyzed Suzuki reaction. Tetrahedron Lett. 2014, 55 (22), 3367-3373.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H227-H315-H319-H335

Combustible liquid. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

주의 설명서: P280g-P305+P351+P338

Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

기타 참조

바일슈타인
1855303
통합 관세 코드
2903.99
TSCA(독성물질규제법)"
Yes

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