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556-56-9 - Allyl iodide, 97+%, stab. with copper - 3-Iodo-1-propene - A11822 - Alfa Aesar

A11822 Allyl iodide, 97+%, stab. with copper

CAS 번호
556-56-9
동의어
3-Iodo-1-propene

사이즈 가격 ($) 수량 재고 여부
50g 78.80
250g 318.00
장바구니에 추가 대량 견적에 추가 항목 보기

Allyl iodide, 97+%, stab. with copper

MDL
MFCD00001094
EINECS
209-130-4

화학적 특성

화학식
C3H5I
화학 식량
167.98
융점
-99°
비등점
101-103°
인화점
18°(64°F)
밀도
1.832
굴절률
1.5540
감도
Light Sensitive
용해도
Soluble in alcohol, chloroform, ether, and diethyl ether. Insoluble in water.

용도

Allyl iodide is used as a reagent used with allylindium sesquiiodide in the cis-double allylation of cyclopropenes. It is used in synthesis of other organic compounds such as N-alkyl 2-pyrrolidone, Sorbic acid ester etc,.

참고

Store at 4°C. Protect from heat. Store away from oxidizing agents. Incompatible with heat, light, amines, nitrides, azo/diazo compounds, alkali metals, and epoxides.

참조 문헌

B. Grzybowska; J. Haber; J. Janas. Interaction of allyl iodide with molybdate catalysts for the selective oxidation of hydrocarbons. Journal of Catalysis.1977, 49 150-163.

Tsuneo Imamoto; Yasuo Hatanaka; Yoshinori Tawarayama; Masataka Yokoyama. Tetrahedron Letters.1981, 49 4987-4988.

Precursor, by reaction with In metal powder, of allylindium reagents which add to alkynes to give 1,4-dienes: J. Org. Chem., 62, 2318 (1997). Allylindiums add to cyclopropenes at the more substituted C atom to give allylcyclopropanes: Tetrahedron Lett., 39, 6317 (1998).

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H225-H314

Highly flammable liquid and vapour. Causes severe skin burns and eye damage.

주의 설명서: P210-P260u-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

Merck
14,294
바일슈타인
1697594
위험 등급
3
포장 그룹
II
통합 관세 코드
2903.39
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
UD0450000

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