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84-58-2 - 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone, 98% - 2,3-Dichloro-5,6-dicyano-p-benzoquinone - 4,5-Dichloro-3,6-dioxo-1,4-cyclohexadiene-1,2-dicarbonitrile - A11879 - Alfa Aesar

A11879 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone, 98%

CAS 번호
84-58-2
동의어
2,3-Dichloro-5,6-dicyano-p-benzoquinone
4,5-Dichloro-3,6-dioxo-1,4-cyclohexadiene-1,2-dicarbonitrile

사이즈 가격 ($) 수량 재고 여부
10g 35.70
50g 120.00
250g 591.00
장바구니에 추가 대량 견적에 추가 항목 보기

2,3-Dichloro-5,6-dicyano-1,4-benzoquinone, 98%

MDL
MFCD00001593
EINECS
201-542-2

화학적 특성

화학식
C8Cl2N2O2
화학 식량
227.01
융점
214-218°
감도
Moisture Sensitive
용해도
Soluble in benzene, methanol, acetic acid and dioxane.Slightly soluble in chloroform,, dichloromethane.

용도

2,3-Dichloro-5,6-dicyano-1,4-benzoquinone is used as a reagent for oxidative couplings and cyclization reactions and dehydrogenation of alcohols, phenols and steroid ketones. It is also used in the synthesis of 1,2-benzisoxazoles. It is a useful electron-transfer reagent for synthesis of quinolines from imines and alkynes or alkenes.

참고

Store in a cool place. Incompatible with strong acids, strong bases, strong oxidizing agents and strong reducing agents.

참조 문헌

Widely used dehydrogenation reagent, e.g. in aromatization reactions; review: Chem. Rev., 67, 153 (1967); 78, 317 (1978). For an example, see: Org. Synth. Coll., 6, 731 (1988). Dehydrogenation of chromanones to chromones and flavanones to flavones: Synthesis, 310 (1983); spirocyclohexenones to the corresponding cross-conjugated dienones: Org. Synth. Coll., 7, 473 (1990).

Catalyzes formation of THP ethers from alcohols: Bull. Chem. Soc. Jpn., 65, 304 (1992), the isopropylidenation of carbohydrates with 2,2-Dimethoxypropane, A13810: Acta Chem. Scand., 47, 843 (1993); and C-N bond formation e.g. imines from arylamines and aldehydes (see also 1,2-Dianilinoethane, B23098), and, with 1 mole of DDQ, benzimidazole formation: Tetrahedron, 51, 5813 (1995):

Silyl and THP ethers are deprotected: J. Chem. Soc., Perkin 1, 2997 (1992); Synth. Commun., 25, 2373 (1995), respectively. Ethers of benzylic or allylic alcohols are oxidized to aldehydes, permitting the use of the methoxymethyl group as a masked aldehyde: Can. J. Chem., 67, 699 (1989). For cleavage of thioacetals to carbonyl groups, see: J. Org. Chem., 58, 7576 (1993); Chem. Lett., 965 (1994).

For a brief feature on uses of the reagent in synthesis, see: Synlett, 196 (2006).

Shehab, O. R.; Mansour, A. M. Sparfloxacin charge transfer complexes with 2, 3-dichloro-5, 6-dicyano-1, 4-benzoquinone and tetracyanoquinodimethane: Molecular structures, spectral, and DFT studies. J. Mol. Struct. 2015, 1093, 186-194.

Uzochukwu, I. C.; Nzegbunam, S. O. Visible Spectrophotometric and Thermodynamic Studies of Diclofenac: Charge-Transfer Complexation with 2, 3 Dichloro-5, 6-dicyano, 1, 4-benzoquinone. Trop. J. Pharm. Res. 2015, 14 (3), 519-525.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H301

Toxic if swallowed.

주의 설명서: P264-P270-P301+P310a-P321-P405-P501a

Wash thoroughly after handling. Do not eat, drink or smoke when using this product. IF SWALLOWED: Immediately call a POISON CENTER/doctor Specific treatment (see label). Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

Merck
14,3063
바일슈타인
747939
위험 등급
6.1
포장 그룹
III
통합 관세 코드
2926.90
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
GU4825000

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