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6622-76-0 - Methyl tiglate, 98% - Methyl trans-2,3-dimethylacrylate - Methyl (E)-2-methyl-2-butenoic acid - A11964 - Alfa Aesar

A11964 Methyl tiglate, 98%

CAS 번호
6622-76-0
동의어
Methyl trans-2,3-dimethylacrylate
Methyl (E)-2-methyl-2-butenoic acid

사이즈 가격 ($) 수량 재고 여부
50g 118.00
250g 480.00
장바구니에 추가 대량 견적에 추가 항목 보기

Methyl tiglate, 98%

MDL
MFCD00016654
EINECS
229-575-8

화학적 특성

화학식
C6H10O2
화학 식량
114.15
비등점
138-139°
인화점
39°(102°F)
밀도
0.950
굴절률
1.4370
용해도
Soluble in alcohol, water 3813 mg/L @ 25°C (est).

용도

It is employed as a perfuming agent in cosmetics industry.

참고

Store away from oxidizing agents. Keep the container tightly closed. Store in cool, dry conditions in well ventilated place.

참조 문헌

Herbert O. House.; Gary H. Rasmusson. Stereoselective. Synthesis of α-Substituted α,β-Unsaturated Esters.J. Org. Chem.,1961,26(11), 4278-4281.

Hirokazu Urabe.; Isao Kuwajima. A cyclopentanone annulation via intramolecular acylation of alkylsilanes.J. Org. Chem.,1984,49(6), 1140-1141.

Lithiation and alkylation with allylic rearrangement with 1-iodo-3-trimethylsilylpropane has been used in a versatile cyclopentanone synthesis: J. Org. Chem., 49, 1140 (1984); Org. Synth. Coll., 8, 486 (1993):

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H226

Flammable liquid and vapour.

주의 설명서: P210-P280a-P240-P241-P303+P361+P353-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves and eye/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

Merck
14,9433
바일슈타인
1720455
위험 등급
3
포장 그룹
III
통합 관세 코드
2916.19
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
EM9254600

권장

  • A12029

    Ethyl tiglate, 98%
  • A12449

    1,8-Diazabicyclo[5.4.0]undec-7-ene, 99%
  • A13301

    Trimethyl phosphonoacetate, 98%
  • A13905

    Tiglic acid, 98+%
  • H59611

    4,4'-Azobis(4-cyanovaleric acid), 98%, cont. ca 18% water

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