Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

108-03-2 - 1-Nitropropane, 98% - A11975 - Alfa Aesar

A11975 1-Nitropropane, 98%

CAS 번호
108-03-2
동의어

사이즈 가격 ($) 수량 재고 여부
250g 37.50
500g 58.50
장바구니에 추가 대량 견적에 추가 항목 보기

1-Nitropropane, 98%

MDL
MFCD00007407
EINECS
203-544-9

화학적 특성

화학식
C3H7NO2
화학 식량
89.09
융점
-108°
비등점
131-132°
인화점
34°(93°F)
밀도
0.998
굴절률
1.4020
용해도
Soluble in water. (1.4 g/L)

용도

The solvent of 1-Nitropropane is mainly used coatings, inks and separation processes.

참고

Store in cool place. Keep away from oxidizing agents.

참조 문헌

T. L. Cottrell.; T. E. Graham.; T. J. Reid. The thermal decomposition of nitroethane and 1-nitropropane. Trans. Faraday Soc. 1951, 471089-1092,.

N. M. M. Nibberin.; Th. J. de Boer.; H. J. Hofman. Mass spectrometry of nitro compounds: Part I: Mass spectra of α-, β- and γ-deuterated 1-nitropropane. Recueil des Travaux Chimiques des Pays-Bas. 1965, 84 (4),481-487.

For an example of condensation with an aldehyde (Henry reaction), promoted by KF in IPA, see: Org. Synth. Coll., 9, 242 (1998). Other conditions recommended for the Henry reaction include the use of the basic ion-exchange resin Amberlyst® A-21, A17956: Liebigs Ann. Chem., 1994, 1235; J. Org. Chem., 59, 5466 (1994); Tetrahedron, 52, 1677 (1996), and aqueous NaOH in the presence of a surfactant-type catalyst (hexadecyltrimethylammmonium chloride): J. Org. Chem., 62, 425 (1997). Improved yields in condensations with cycloalkanones were obtained by the use of high pressure: Angew. Chem. Int. Ed., 23, 617 (1984).

Primary nitro-compounds are converted to nitrile oxides by reaction with POCl3 in pyridine: J. Org. Chem., 42, 3956 (1977). For example of 1,3-dipolar addition reaction of the nitrile oxide to give an isoxazole, see Ethyl­ (E)-3-(1-pyrrolidinyl)­crotonate, L00461.

For discussion of conditions for formation and chemistry of the ɑɑ- and ɑß- dilithio derivatives, see: Encyclopedia of Reagents for Organic Synthesis, L. A. Paquette, Ed., Wiley, Chichester (1995), vol. 3, p. 1946.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H226-H302-H312-H332

Flammable liquid and vapour. Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled.

주의 설명서: P210-P261-P280-P303+P361+P353-P304+P340-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

Merck
14,6627
바일슈타인
506236
위험 등급
3
포장 그룹
III
통합 관세 코드
2904.20
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
TZ5075000

권장

최근에 본 것

화학물질

화학물질

금속 및 재료

촉매

분석 기기 및 실험실 용품