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93-17-4 - 3,4-Dimethoxyphenylacetonitrile, 98% - 3,4-Dimethoxybenzyl cyanide - Homoveratronitrile - A12003 - Alfa Aesar

A12003 3,4-Dimethoxyphenylacetonitrile, 98%

CAS 번호
93-17-4
동의어
3,4-Dimethoxybenzyl cyanide
Homoveratronitrile

사이즈 가격 ($) 수량 재고 여부
25g 17.70
100g 37.50
500g 151.00
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3,4-Dimethoxyphenylacetonitrile, 98%

MDL
MFCD00001911
EINECS
202-225-1

화학적 특성

화학식
C10H11NO2
화학 식량
177.20
융점
62-65°
비등점
177-178°/10mm
용해도
Insoluble in water. Soluble in methanol.

용도

It is employed as an intermediate in the preparation of the muscle relaxant papverin. 3,4-Dimethoxyphenyl)acetonitrile has been used in the synthesis of (Z)-3-(benzo[b]thiophen-2-yl)-2-(3,4-dimethoxyphenyl)acrylonitrile1. It has also been used in the preparation of modified diterpene (±) nimbidiol which relies on a sulfenium ion promoted polyene cyclization.

참고

Store in cool place. Keep away from oxidizing agents.

참조 문헌

Eide-Dittmar Luebs.; Alberto Cohen.; Edward J. Zaleski.; Richard J. Bing. Effect of nitroglycerin, intensain, isoptin and papaverine on coronary blood flow in man ?: Measured by the coincidence counting technic and rubidium. The American Journal of Cardiology. 1966, 17 (4),535-541.

A. Carpy, J.-M. Léger.; C. Melchiorre. Structure of [alpha]-isopropyl-[alpha]-[(N-methyl-N-homoveratryl)-[gamma]-aminopropyl]-3,4-dimethoxyphenylacetonitrile hydrochloride, verapamil, C27H38N2O4.HCl. Acta Cryst. 1985, (C41),624-627.

Reaction with dimethylamine in the presence of CuCl gives the N,N-dimethylamidine, which, on borohydride reduction, provides an efficient route to the N,N-dimethylphenethylamine: Tetrahedron Lett., 34, 6395 (1993); Org. Synth., 76, 133 (1998). The method is applicable to other alkyl nitriles and to both primary and secondary amines, providing a general route to secondary and tertiary amines from the corresponding nitriles:

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H302-H312

Harmful if swallowed. Harmful in contact with skin.

주의 설명서: P280h

Wear protective gloves/clothing.

기타 참조

바일슈타인
1956100
통합 관세 코드
2926.90
TSCA(독성물질규제법)"
No
RTECS(화학물질 독성 등록)
AL9325000

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