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352-34-1 - 1-Fluoro-4-iodobenzene, 99% - 4-Fluoroiodobenzene - A12008 - Alfa Aesar

A12008 1-Fluoro-4-iodobenzene, 99%

CAS 번호
352-34-1
동의어
4-Fluoroiodobenzene

사이즈 가격 ($) 수량 재고 여부
10g 23.90
50g 114.00
250g 463.00
장바구니에 추가 대량 견적에 추가 항목 보기

1-Fluoro-4-iodobenzene, 99%

MDL
MFCD00001052
EINECS
206-522-7

화학적 특성

화학식
C6H4FI
화학 식량
222.00
융점
-20°
비등점
182-184°
인화점
68°(154°F)
밀도
1.925
굴절률
1.5830
감도
Light Sensitive
용해도
Insoluble in water.

용도

4-Fluoroiodobenzene was used in the preparation of fluorotriphenylene derivatives. 4-[F] Fluoroiodobenzene is a versatile building block in 18F radiochemistry and is used in various transition metal-mediated C-C and C-N cross-coupling reactions.

참고

Light Sensitive. Store in cool dry place. Keep container tightly sealed.

참조 문헌

Jerry M. Meyersa.; Andrew J. Gellman. Effect of substituents on the phenyl coupling reaction on Cu(111).Surface Science. 1995, 337 (1-2), 40-50.

Hülya Akgün.; Tomas Hudlicky. Total syntheses of ert-conduramine A and ent-7-deoxypancratistatin. Tetrahedron Lett. 1999, 40 (16),3081-3084.

Regioselective metallation can be accomplished with LDA ortho to the fluoro substituent: Tetrahedron Lett., 33, 7499 (1992). Subsequent carboxylation and F - displacement with an amine has been used to synthesize 5-iodoanthranilic acid derivatives: J. Med. Chem., 40, 717 (1997).

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H227-H315-H319-H335

Combustible liquid. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

주의 설명서: P210u-P261-P280a-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

바일슈타인
1853970
통합 관세 코드
2903.99
TSCA(독성물질규제법)"
Yes

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