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630-18-2 - Trimethylacetonitrile, 98+% - tert-Butyl cyanide - Pivalonitrile - A12011 - Alfa Aesar

A12011 Trimethylacetonitrile, 98+%

CAS 번호
630-18-2
동의어
tert-Butyl cyanide
Pivalonitrile

사이즈 가격 ($) 수량 재고 여부
25g 58.30
100g 174.00
장바구니에 추가 대량 견적에 추가 항목 보기

Trimethylacetonitrile, 98+%

MDL
MFCD00001847
EINECS
211-133-0

화학적 특성

화학식
(CH3)3CCN
화학 식량
83.13
융점
16-18°
비등점
105-106°
인화점
4°(39°F)
밀도
0.757
용해도
Miscible with ethanol, acetone and toluene. Slightly miscible with water.

용도

Trimethylacetonitrile used as a solvent and as a labile ligand in coordination chemistry. It is also used as an intermediate in organic synthesis. It is used in the presence of titanium(II) chloride and zinc to undergoes reductive coupling reaction of aromatic and aliphatic ketones including acyclic aliphatic ketones to give the corresponding pinacols.

참고

Store in a cool place. Incompatible with strong acids, strong bases, strong oxidizing agents and strong reducing agents.

참조 문헌

For in situ reaction with vinyl triflates in the synthesis of sterically hindered 2,4,6-trisubstituted pyrimidines, see: Synthesis, 881 (1990); for reaction scheme, see Trifluoromethanesulfonic acid, A1173 .

Bagal, D. B.; Bhanage, B. M. Recent Advances in Transition Metal-Catalyzed Hydrogenation of Nitriles. Adv. Synth. Catal. 2015, 357 (5), 883-900.

Akhtar, N.; Akhtar, W. Prospects, challenges, and latest developments in lithium-air batteries. Int. J. Energy Res. 2015, 39 (3), 303-316.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H225-H302-H312-H332-H315-H319-H335

Highly flammable liquid and vapour. Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

주의 설명서: P210-P261-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

위험 등급
3
포장 그룹
II
통합 관세 코드
2926.90
TSCA(독성물질규제법)"
Yes

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