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17564-64-6 - N-(Chloromethyl)phthalimide, 97% - A12018 - Alfa Aesar

A12018 N-(Chloromethyl)phthalimide, 97%

CAS 번호
17564-64-6
동의어

사이즈 가격 ($) 수량 재고 여부
25g 58.50
100g 221.00
장바구니에 추가 대량 견적에 추가 항목 보기

N-(Chloromethyl)phthalimide, 97%

MDL
MFCD00005898
EINECS
241-541-4

화학적 특성

화학식
C9H6ClNO2
화학 식량
195.61
융점
131-135°
용해도
Insoluble in water.

용도

It is used as an agrochemical and medicine intermediates and is used in organic synthesis. Microporous membranes prepared from chemically modified polysulfone, which is a derivative of this compound have better streaming potential.

참고

Store in cool place. Keep away from oxidizing agents. Incompatible with bases.

참조 문헌

Ekkehard Hinke.; Eberhard Staude. Streaming potential of microporous membranes made from homogeneously functionalized polysulfone. J. Appl. Polym. Sci. 1991, 42 (11),2951-2958.

M. Hariharan.; S. Chaberek.; A. E. Martella. Synthesis of Phosphonopeptide Derivatives. Synth. Commun. 1973, 3 (5),375-379.

Reagent for carboxyl protection, e.g. in peptide synthesis, by reaction in the presence of an amine: Rec. Trav. Chim., 82, 941 (1963); or with KF in DMF: Synth. Commun., 8, 515 (1978). The phthalimidomethyl ester can be cleaved in various ways including hydrazinolysis, HBr in acetic acid or Zn/AcOH. See also N-(Hydroxymethyl)­phthalimide, B21292 and Appendix 6.

Also reported for the protection of thiols as the S-phthalimidomethyl (Pim) derivative. Cleavage is by hydrazinolysis, followed by Hg(II), Cu(II) or I2: Chem. Lett., 2139 (1994).

Reagent for the amidomethylation of aromatic systems. For reviews of amidomethylation, see: Org. React., 14, 52 (1965); Synthesis, 49 (1970); 85, 181 (1984).

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

주의 설명서: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

바일슈타인
140942
통합 관세 코드
2925.19
TSCA(독성물질규제법)"
Yes

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