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455-13-0 - 4-Iodobenzotrifluoride, 98% - 4-Iodo-alpha,alpha,alpha-trifluorotoluene - A12189 - Alfa Aesar

A12189 4-Iodobenzotrifluoride, 98%

CAS 번호
455-13-0
동의어
4-Iodo-alpha,alpha,alpha-trifluorotoluene

사이즈 가격 ($) 수량 재고 여부
1g 25.90
5g 74.20
25g 266.00
장바구니에 추가 대량 견적에 추가 항목 보기

4-Iodobenzotrifluoride, 98%

MDL
MFCD00039398
EINECS
207-234-4

화학적 특성

화학식
C7H4F3I
화학 식량
272.01
융점
-8°
비등점
68-70°/15mm
인화점
68°(154°F)
밀도
1.851
굴절률
1.5180
감도
Light Sensitive
용해도
Insoluble in water.

용도

4-Iodobenzotrifluoride may be employed as substrate with electron-deficient aromatic ring, during Mizoroki-Heck reaction with acrylic acid, to afford 4-trifluoromethylcinnnamic acid. It undergoes aminocarbonylation in DMF using phosphoryl chloride to give N,N-dimethyl-(4-trifluoromethyl)benzamide.

참고

Light sensitive. Incompatible with strong oxidizing agents. Store in dark.

참조 문헌

Atsushi Ohtaka; Tomohiro Yamaguchi; Takuto Teratani; Osamu Shimomura; Ryôki Nomura. Linear polystyrene-stabilized PdO nanoparticle-catalyzed Mizoroki-Heck reactions in water. Molecules. 2011, 16 (11), 9067-9076.

Kazushi Hosoi; Kyoko Nozaki; Tamejiro Hiyama. Carbon monoxide free aminocarbonylation of aryl and alkenyl iodides using DMF as an amide source. Organic Letters. 2002, 4 (17), 2849-2851.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H227-H315-H319-H335

Combustible liquid. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

주의 설명서: P210u-P261-P280a-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

바일슈타인
1944013
통합 관세 코드
2903.99
TSCA(독성물질규제법)"
Yes

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