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86-93-1 - 1-Phenyl-1H-tetrazole-5-thiol, 99% - 5-Mercapto-1-phenyl-1H-tetrazole - A12656 - Alfa Aesar

A12656 1-Phenyl-1H-tetrazole-5-thiol, 99%

CAS 번호
86-93-1
동의어
5-Mercapto-1-phenyl-1H-tetrazole

사이즈 가격 ($) 수량 재고 여부
25g 34.20
100g 125.00
500g 534.00
장바구니에 추가 대량 견적에 추가 항목 보기

1-Phenyl-1H-tetrazole-5-thiol, 99%

MDL
MFCD00003129
EINECS
201-710-5

화학적 특성

화학식
C7H6N4S
화학 식량
178.22
융점
ca 145° dec.
인화점
138°(280°F)
감도
Air Sensitive
용해도
Soluble in 5% ethanol, water (partly), acetone, chloroform, and methanol.

용도

1-Phenyl-1H-tetrazole-5-thiol is an effective inhibitor of aluminum corrosion in 1M HCl solution. 1-Phenyl-1H-tetrazole-5-thiol was used in the synthesis of oxacyclic building blocks via highly stereoselective radical cyclization and olefin metathesis reactions. It was also used in the synthesis of metalated tetradecyl sulfone. It is also used in the spectrophotometric determination of Pt and Bi.

참고

Air Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Stable under recommended storage conditions. Keep away from oxidizing agents.

참조 문헌

R Cea-Olivares.; OJ Sandoval.; G Espinosa-Perez. New organotin(IV) derivatives of 1-phenyl-1H-tetrazole-5-thiol. Crystal and molecular structure of 1?[Bz3SnSCN4Ph], a polymer built through secondary intermolecular Sn?N bonds. Polyhedron. 2008, 13, (19), 2809-2818.

C Ma.; J Sun. Hydrogen bonding and π-π stacking interaction in the coordination of sulfur and nitrogen donor heterocycle to organotin(IV): syntheses and crystal structures of di- and triorganotin(IV) derivatives with 1-(4-hydroxyphenyl)-1H-tetrazole-5-thiol. Polyhedron. 2004, 23, (9), 2809-2818.

In combination with t-butyl isocyanide, promotes the lactonization of long-chain hydroxy acids: Angew. Chem. Int. Ed., 20, 771 (1981).

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H228-H302

Flammable solid. Harmful if swallowed.

주의 설명서: P210-P280a-P240-P241-P301+P312a-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves and eye/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

바일슈타인
139068
위험 등급
4.1
포장 그룹
III
통합 관세 코드
2933.99
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
XF7700000

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