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5219-61-4 - (Phenylthio)acetonitrile, 98% - Cyanomethyl phenyl sulfide - Phenylmercaptoacetonitrile - A12869 - Alfa Aesar

A12869 (Phenylthio)acetonitrile, 98%

CAS 번호
5219-61-4
동의어
Cyanomethyl phenyl sulfide
Phenylmercaptoacetonitrile

사이즈 가격 ($) 수량 재고 여부
5g 56.10
25g 202.00
100g 722.00
장바구니에 추가 대량 견적에 추가 항목 보기

(Phenylthio)acetonitrile, 98%

MDL
MFCD00019831
EINECS
226-013-3

화학적 특성

화학식
C6H5SCH2CN
화학 식량
149.22
비등점
146-147°/14mm
인화점
>110°(230°F)
밀도
1.142
굴절률
1.5820
용해도
Not miscible or difficult to mix in water.

용도

Applications include, electron-deficient aromatics undergo vicarious nucleophilic substitution (VNS) reactions with the anion. Thus the molecule is equivalent to an acetonitrile anion synthon with thiophenate as the leaving group. For example, in the presence of solid NaOH in DMSO, nitrobenzene gives predominantly 4-nitrophenylacetonitrile, along with some of the 2-isomer.

참고

Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

참조 문헌

Shuji Kanemasa, et al. Generation of Sulfur-Functionalized Nitrile Oxide, (Phenylthio)acetonitrile Oxide, and Synthetic Applications.Bulletin of the Chemical Society of Japan.,1988,61(11), 3973-3982.

V. Suryanarayanan, et al. Selective electrofluorination of phenylacetonitrile and α-(phenylthio) acetonitrile — The role of sulfur and other operating parameters.Journal of Fluorine Chemistry.,1998,91(2), 153-157.

Electron-deficient aromatics undergo vicarious nucleophilic substitution (VNS) reactions with the anion. Thus the molecule is equivalent to an acetonitrile anion synthon with thiophenate as the leaving group. For example, in the presence of solid NaOH in DMSO, nitrobenzene gives predominantly 4-nitrophenylacetonitrile, along with some of the 2-isomer: J. Org. Chem., 45, 1534 (1980).

Electrochemical ɑ-monofluorination with Triethyl­amine trihydrofluoride, L14417 occurs in good yield: J. Org. Chem., 60, 3459 (1995).

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H302

Harmful if swallowed.

주의 설명서: P280f

Wear protective clothing.

기타 참조

바일슈타인
2042078
통합 관세 코드
2930.90
TSCA(독성물질규제법)"
No
RTECS(화학물질 독성 등록)
AM1900000

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