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645-96-5 - Phenylselenol, 90+% - Benzeneselenol - Selenophenol - A12876 - Alfa Aesar

A12876 Phenylselenol, 90+%

CAS 번호
645-96-5
동의어
Benzeneselenol
Selenophenol

사이즈 가격 ($) 수량 재고 여부
1g 51.40
5g 176.00
25g 720.00
장바구니에 추가 대량 견적에 추가 항목 보기

Phenylselenol, 90+%

MDL
MFCD00000001
EINECS
211-457-2

화학적 특성

화학식
C6H6Se
화학 식량
157.07
비등점
71-72°/18mm
인화점
70°(158°F)
밀도
1.479
굴절률
1.6120
감도
Air Sensitive
용해도
Not miscible or difficult to mix in water.

용도

It is applied for reactions of phenylselenol and its anion. Benzeneselenol can used as starting reagent in the synthesis of monoseleno-substituted 1,3-dienes. It may be used in the synthesis of cationic chalcogenolato-bridged diruthenium complexes.

참고

Air sensitive. Store away from oxidizing agents and air. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas.

참조 문헌

Nikolay V Orlov et. al. Exclusive selectivity in the one-pot formation of C-C and C-Se bonds involving Ni-catalyzed alkyne hydroselenation: optimization of the synthetic procedure and a mechanistic study.J Org Chem.,2014,79(24), 12111-12121.

R.J. Puddephatt and P.J. Thompson. Some reactions of methylplatinum and methylgold compounds with phenylselenol, diphenylphosphine, diphenylarsine, N-bromosuccinimide and 2-nitrophenylsulphenyl chloride.J. Organomet. Chem.,1976,117(4), 395-403.

For reactions of phenylselenol and its anion, see Diphenyl­ diselenide, A13919.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H227-H301-H331-H373

Combustible liquid. Toxic if swallowed. Toxic if inhaled. May cause damage to organs through prolonged or repeated exposure.

주의 설명서: P210u-P260-P280a-P301+P310a-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF SWALLOWED: Immediately call a POISON CENTER/doctor Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

바일슈타인
385715
위험 등급
6.1
포장 그룹
II
통합 관세 코드
2931.90
TSCA(독성물질규제법)"
Yes

권장

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