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107-13-1 - Acrylonitrile, 99+%, stab. with ca 40ppm 4-methoxyphenol - Propenenitrile - Vinyl cyanide - A13058 - Alfa Aesar

A13058 Acrylonitrile, 99+%, stab. with ca 40ppm 4-methoxyphenol

CAS 번호
107-13-1
동의어
Propenenitrile
Vinyl cyanide

사이즈 가격 ($) 수량 재고 여부
100ml 15.00
500ml 23.50
2500ml 70.00
장바구니에 추가 대량 견적에 추가 항목 보기

Acrylonitrile, 99+%, stab. with ca 40ppm 4-methoxyphenol

MDL
MFCD00001927
EINECS
203-466-5

화학적 특성

화학식
C3H3N
화학 식량
53.06
융점
-84°
비등점
77-78°
인화점
0°(32°F)
밀도
0.806
굴절률
1.3910
감도
Light Sensitive
용해도
Miscible with isopropanol, ethanol, ether, acetone, water, carbon tetrachloride, ethyl acetate, toluene and benzene.

용도

Acrylonitrile acts as a monomer used in the production of polyacrlonitrile plastics, adhesives and synthetic rubber. It is also used for the synthesis of copolymers such as styrene-acrylonitrile, acrylonitrile butadiene styrene, acrylonitrile styrene acrylate. It is involved in the preparation of adiponitrile by dimerization, which finds application in polyamide synthesis. It acts as a precursor to acrylamide and acrylic acid. It is used as dienophile in Diels-Alder reactions. It acts as a chemical intermediate in the synthesis of antioxidants, active pharmaceutical ingredients, dyes, and surface-active agents. Further, it is utilized for the preparation of acrylic fibers, resins and nitrile rubbers. In addition to this, it serves as a fumigant for food commodities, flour milling, and bakery food processing equipment.

참고

Light sensitive. Incompatible with oxidizing agents, acids, alkalis, metals, bromine, peroxides and copper.

참조 문헌

The Stetter reaction (conjugate addition of aryl aldehydes) catalyzed by CN-, is exemplified by the addition of pyridine-3-carboxaldehyde to acrylonitrile to give 4-oxo-4-(3-pyridyl)butyronitrile: Org. Synth. Coll., 6, 866 (1988). See also 3-Benzyl-5-(2-hydroxyethyl)-4-methyl­thiazolium chloride, L08750.

Free radical alkylation, acylation and arylation reactions also occur in the presence of t-butyl hydroperoxide and a Cu(II) catalyst: J. Chem. Soc., Chem. Commun., 1399 (1995). Several other free radical procedures have been reported involving intramolecular homolytic aromatic substitution to give carbocyclic and heterocyclic systems: Tetrahedron Lett., 36, 4307 (1995):

The reaction is also applicable to acrylate esters and vinyl ketones; with acrylonitrile and phenoxyacetic acid, tetrahydrobenzopyran-4-carbonitrile is obtained in 41% yield.

Dai, Y.; Song, Y.; Tu, X.; Jiang, Y.; Yuan, Y. Sequential shape-selective adsorption and photocatalytic transformation of acrylonitrile production wastewater. Water Res. 2015, 85, 216-225.

Pan, X.; Lamson, M.; Yan, J.; Matyjaszewski, K. Photoinduced Metal-Free Atom Transfer Radical Polymerization of Acrylonitrile. ACS Macro Lett. 2015, 4 (2), 192-196.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H225-H301-H311-H331-H315-H318-H317-H350-H335

Highly flammable liquid and vapour. Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. Causes skin irritation. Causes serious eye damage. May cause an allergic skin reaction. May cause cancer. May cause respiratory irritation.

주의 설명서: P210-P301+P310a-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF SWALLOWED: Immediately call a POISON CENTER/doctor IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

Merck
14,131
바일슈타인
605310
위험 등급
3
포장 그룹
I
통합 관세 코드
2926.10
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
AT5250000

권장

  • A13128

    Methyl acrylate, 99%, stab. with ca 15ppm 4-methoxyphenol
  • A16163

    Formaldehyde, 37% w/w aq. soln., stab. with 7-8% methanol
  • A18481

    Styrene, 99%, stab. with 10-15ppm 4-tert-butylcatechol
  • B24815

    2-Hydroxyethyl acrylate, 97%, stab. with 200-300ppm 4-methoxyphenol
  • L02637

    1-Hexadecene, 94%

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