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82911-69-1 - N-(9-Fluorenylmethoxycarbonyloxy)succinimide, 98% - 9-Fluorenylmethyl N-succinimidyl carbonate - Fmoc-ONSu - A13143 - Alfa Aesar

A13143 N-(9-Fluorenylmethoxycarbonyloxy)succinimide, 98%

CAS 번호
82911-69-1
동의어
9-Fluorenylmethyl N-succinimidyl carbonate
Fmoc-ONSu

사이즈 가격 ($) 수량 재고 여부
1g 22.70
5g 60.90
25g 240.00
장바구니에 추가 대량 견적에 추가 항목 보기

N-(9-Fluorenylmethoxycarbonyloxy)succinimide, 98%

MDL
MFCD00010733
EINECS
433-520-5

화학적 특성

화학식
C19H15NO5
화학 식량
337.34
융점
150-153°
감도
Moisture Sensitive
용해도
Soluble in dimethyl sulfoxide and dimethyl formamide.

용도

N-(9-Fluorenylmethoxycarbonyloxy)succinimide is the most efficient reagent for the selective preparation of N-(9-fluorenylmethoxycarbonyl) derivatives of hydroxy-amino acids. Dipeptide formation is lower than with the chloroformate, Fmoc-Cl. It is also employed in the synthesis of glycopeptides.

참고

Store in a cool place. Moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong acids.

참조 문헌

Reagent for the preparation of Fmoc derivatives of amino acids, avoiding problems arising from mixed anhydride formation; preferred especially for the protection of hydroxy amino acids: Can. J. Chem., 60, 976 (1982); Biopolymers, 22, 2157 (1983); Synthesis, 671 (1978). For peptide reagents, see Appendix 6.

Bartolami, E.; Gilles, A.; Dumy, P.; Ulrich, S. Synthesis of alpha-PNA containing a functionalized triazine as nucleobase analogue. Tetrahedron Lett. 2015, 56 (18), 2319-2323.

Wang, N.; Seko, A.; Takeda, Y.; Ito, Y. Preparation of asparagine-linked monoglucosylated high-mannose-type oligosaccharide from egg yolk. Carbohydr. Res. 2015, 411, 37-41.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H302-H317

Harmful if swallowed. May cause an allergic skin reaction.

주의 설명서: P261-P280g-P301+P312a-P363-P321-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves. IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Wash contaminated clothing before reuse. Specific treatment (see label). Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

바일슈타인
3569540
위험 등급
9
포장 그룹
III
통합 관세 코드
2925.19
TSCA(독성물질규제법)"
No

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