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693-02-7 - 1-Hexyne, 98+% - n-Butylacetylene - A13156 - Alfa Aesar

A13156 1-Hexyne, 98+%

CAS 번호
693-02-7
동의어
n-Butylacetylene

사이즈 가격 ($) 수량 재고 여부
10g 22.40
50g 65.60
250g 264.00
장바구니에 추가 대량 견적에 추가 항목 보기

1-Hexyne, 98+%

MDL
MFCD00009504
EINECS
211-736-9

화학적 특성

화학식
CH3(CH2)3C≡CH
화학 식량
82.15
융점
-132°
비등점
69-71°
인화점
-21°(-5°F)
밀도
0.718
굴절률
1.3990
용해도
Miscible with organic solvents. Immiscible with water.

용도

1-Hexyne is used in the preparation of tricyclic isoindolinone scaffold by undergoing hydrozirconation and ring-closing metathesis. It is used to prepare trans-1,2-bis(5-thianthreniumyl)alkene tetrafluoroborate by reacting with thianthrene cation radical tetrafluoroborate.

참고

Incompatible with strong oxidizing agents, strong reducing agents, strong acids and strong bases.

참조 문헌

The dilithiation of 1-alkynes with n-BuLi, followed by alkylation at the 3-position, is illustrated for 1-hexyne: Org. Synth. Coll., 6, 595 (1988). For [2 + 2] cycloaddition with dichloroketene to give a substituted cyclobutenone, see: Org. Synth. Coll., 8, 82 (1993).

Van, D. D.; Hosokawa, T.; Saito, M.; Horiuchi, Y.; Matsuoka, M. A heterogeneous mesoporous silica-supported cyclopentadienyl ruthenium(II) complex catalyst for selective hydrosilylation of 1-hexyne at room temperature. Appl. Catal., A. 2015, 503, 203-208.

Saito, M.; Watanabe, T.; Kamegawa, T.; Horiuchi, Y.; Matsuoka, M. Construction of an organoruthenium complex (-[biphRuCp]PF6-) within a biphenylene-bridged inorganic-organic hybrid mesoporous material, and its catalytic activity in the selective hydrosilylation of 1-hexyne. Res. Chem. Intermed. 2014, 40 (1), 105-113.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H225-H304

Highly flammable liquid and vapour. May be fatal if swallowed and enters airways.

주의 설명서: P210-P273-P243-P301+P330+P331-P315

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid release to the environment. Take precautionary measures against static discharge. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Get immediate medical advice/attention.

기타 참조

바일슈타인
635687
위험 등급
3
포장 그룹
II
통합 관세 코드
2901.29
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
MQ9691000

권장

최근에 본 것

화학물질

화학물질

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